S. Mirshrkari; V. Shojaei; H. Khoshdast
Abstract
A coal waste sample loaded with Fe3O4 nanoparticles is employed as an efficient adsorbent to remove Cd from synthetic wastewater. The synthesized nanocomposite is characterized using the Fourier transform-infrared (FT-IR), X-ray diffraction (XRD), and transmission electron microscopy (TEM) techniques. ...
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A coal waste sample loaded with Fe3O4 nanoparticles is employed as an efficient adsorbent to remove Cd from synthetic wastewater. The synthesized nanocomposite is characterized using the Fourier transform-infrared (FT-IR), X-ray diffraction (XRD), and transmission electron microscopy (TEM) techniques. The visual analysis of the microscopic image shows that the mean size of the magnetite nanoparticles is about 10 nm. The effects of the operating variables of the initial solution pH (3-11) and nanocomposite to pollutant ratio (7-233) are evaluated using the response surface methodology on cadmium adsorption. The process is also optimized using the quadratic prediction model based on the central composite design. The statistical analysis reveals that both factors play a significant role in Cd adsorption. The maximum Cd removal of 99.24% is obtained under optimal operating conditions at pH 11 and nanocomposite/cadmium ratio of 90 after 2 h of equilibrium contact time. A study of the adsorption kinetics indicates that the maximum removal could be attained in a short time of about 2 min following a first-order model. The isotherm investigations present that the Cd adsorption on the Fe3O4/coal waste nanocomposite has a linearly descending heat mechanism based on the Temkin isotherm model with the minor applicability parameters than the other isotherm models. The overall removal behaviour is attributed to a two-step mechanism including a rapid adsorption of cadmium ion onto the active sites at the surface of nanocomposite followed by a slow cadmium hydroxide precipitation within the pores over the nanocomposite surface.
Mineral Processing
H. Paryad; H. Khoshdast; V. Shojaei
Abstract
It is well-known that entrainment of particles into the froth is a key factor in the selectivity and performance of the flotation process, especially for fine particle recovery. Since flotation is a continuous process, in this work, the effects of operating parameters on the entrainment of ash materials ...
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It is well-known that entrainment of particles into the froth is a key factor in the selectivity and performance of the flotation process, especially for fine particle recovery. Since flotation is a continuous process, in this work, the effects of operating parameters on the entrainment of ash materials in a sample coal flotation is investigated from a time-sequence viewpoint. The effects of the pulp solid content, collector concentration, frother concentration, impeller speed, and particle size on the entrainment factor and water recovery at different flotation times are evaluated using a D-optimal response surface experimental design. The experimental work carried out shows that some parameters, especially particle size and pulp density, can yield completely different responses from those reported in the literature. The observed unusual behaviours can be attributed to the entrainment mechanisms and verified by the experimental results. It is also shown that the dominant entrainment mechanism can be varied by time. In addition, the statistical analyses of the experimental design show that the effects of some parameters change during time from the initial to the final stages of the flotation process. The results obtained indicate that the particle size and pulp density are the most important parameters influencing the entrainment rate and water recovery. The effects of the collector and frother concentrations are less on the entrainment and water recovery. In addition, the interaction between the solid percentage and particle size is the only significant mixed effect.