Mineral Processing
A.H. Rezaei; H. Abdollahi; M. Gharabaghi; A. A. Mohammadzadeh
Abstract
In the recent decades, water scarcity has become a major challenge for many reasons, especially the inadequate use of water resources. The mineral processing plant is among the most important water-consuming industries. Filtration, as one of the important processes in water recovery, is a process in ...
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In the recent decades, water scarcity has become a major challenge for many reasons, especially the inadequate use of water resources. The mineral processing plant is among the most important water-consuming industries. Filtration, as one of the important processes in water recovery, is a process in which the solid-suspended particles are removed from the liquid. In the present work, the effect of the additives affecting the filtration process upon the responses including the resistance to filter cloth (R), specific cake resistance (α), moisture content, water recovery rate, and cake formation rate by the vacuum top-feed method is investigated. The experiments are performed by two methodologies: one-factor-at-a-time and statistical analysis. The additives are the flocculant, coagulant, surfactant, and filter aid. According to the one-factor-at-a-time methodology, the optimal type and dosage of the variables are as follow: flocculant A25 with a concentration of 15 g/L, perlite as the filter aid with an amount of 2.5%, surfactant cop 20-101 with a concentration of 3 cc/L, and the coagulant CaCl2.2H2O with a concentration of 2.5 g/L. The usage of the flocculant, surfactant, and filter aid at the same time is also statistically analyzed with the aim of maximizing the cake formation rate and minimizing the moisture content of the filter cake. Under the optimal conditions and taking into account 11.68 g/t of the flocculant A25, 3.8% of perlite as the filter aid, and2.92 cc/L of the surfactant cop 20-101, the cake formation rate and the moisture content were obtained to be 0.297 mm/s and 12.7 %, respectively.
Mineral Processing
H. Jafari; H. Abdollahi; M. Gharabaghi; A.A. Balesini
Abstract
In this research work, solvent extraction and stripping of zinc ions from a Zn-Mn-Cd-bearing solution was investigated using D2EHPA as the extractant in a chloride medium. The efficiency of the extraction and stripping stages was evaluated separately, and different parameters such as the pH, extractant ...
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In this research work, solvent extraction and stripping of zinc ions from a Zn-Mn-Cd-bearing solution was investigated using D2EHPA as the extractant in a chloride medium. The efficiency of the extraction and stripping stages was evaluated separately, and different parameters such as the pH, extractant concentration, reaction temperature, and contact time were studied. Based on the results obtained, 97% of zinc, 14% of manganese, and 3% of cadmium were extracted at pH = 2.5, 10% (v/v) of D2EHPA, and 40 °C from the solution containing 5 g L-1 of each metal ion. The stripping isotherms of zinc, manganese, and cadmium at different pH values showed that manganese and zinc were stripped at two different pH values. Thus more than 70% of manganese and more than 90% of zinc were stripped at pH = 2.5 and pH = 0.5, respectively. Kinetic studies indicated that the extraction and stripping of zinc in the first 0.5-1 minute was high. The McCabe–Thiele diagrams showed that two stages of extraction and two stages of stripping in the continuous counter-current flow condition were adequate to separate zinc from Mn and Cd. The dominant Zn species extracted by D2EHPA was ZnCl+, and the values for the thermodynamic parameters ΔHo, ΔSo, and ΔGo were 25.65 kJ mol−1, 79.20 J K−1 mol−1, and 0.86 kJ mol−1, respectively, which showed that the reaction was endothermic at equilibrium.
