Mineral Processing
S. Shahraki; M. Karamoozian; A. Azizi
Abstract
Sulfur is one of the most significant impurities in coal, which reduces the quality of coal and also results in environmental pollution. This work was aimed to investigate the removal of sulfur from coal by the leaching method employing parameters expected to affect the removal rate such as acid concentration ...
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Sulfur is one of the most significant impurities in coal, which reduces the quality of coal and also results in environmental pollution. This work was aimed to investigate the removal of sulfur from coal by the leaching method employing parameters expected to affect the removal rate such as acid concentration (10-30%), temperature (40-80 °C), and reaction time (40-100 min). A response surface methodology using Box-Behnken design was employed to maximize, model, and evaluate the factors affecting the desulfurization process. The results obtained indicated that the desulfurization value increased with increase in the acid concentration, temperature, and reaction time. A quadratic model with a high correlation coefficient (R2=0.98) is proposed and developed for the relationship between the removal value and the influential factors. The modeling results demonstrated that the significance degree of factors was in the order of acid concentration>temperature>reaction time. It was also found that the maximum desulfurization (about 87%) could be obtained under the optimal conditions of acid concentration=25%, temperature=80 °C, and leaching time=84 minutes.
Asghar Azizi; Ali Dehghani; Seyyed Zioddin Shafaei
Abstract
AbstractThe purpose of this study was to investigate the controllable operating parameters influence, including pH, solid content, collector, co-collector, and depressant dose, and conditioning time, on apatite flotation kinetics. Four first order flotation kinetic models are tested on batch flotation ...
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AbstractThe purpose of this study was to investigate the controllable operating parameters influence, including pH, solid content, collector, co-collector, and depressant dose, and conditioning time, on apatite flotation kinetics. Four first order flotation kinetic models are tested on batch flotation time-recovery profiles. The results of batch flotation tests and the fitting of first-order kinetic models to assess the influence of operating parameters on the flotation kinetics indicated that model with fast and slow - floating components and classical model gave the best and the worst fit for experimental data, respectively. Also, rectangular distribution of floatabilities and gamma distribution of floatabilities fitted the experimental data well. In this study, the model with rectangular distribution of floatabilities associated with fractional factorial experimental design was employed to evaluate the effect of six main parameters on kinetic parameters (R_∞, K). The result indicated that linear effects of depressant dose, conditioning time, and the interaction effects of solid concentration and pH statistically were important on ultimate recovery but the significant parameters for flotation rate constant were linear effects of solids content, depressant dosage and the interaction effect between pH and conditioning time. Regression equations obtained to relate between flotation operation and kinetic parameters.
