Exploitation
F. Soltani; P. Moarefvand; F. Alinia; P. Afzal
Abstract
The traditional approaches of modeling and estimation of highly skewed deposits have led to incorrect evaluations, creating challenges and risks in resource management. The low concentration of the rare earth element (REE) deposits, on one hand, and their strategic importance, on the other, enhances ...
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The traditional approaches of modeling and estimation of highly skewed deposits have led to incorrect evaluations, creating challenges and risks in resource management. The low concentration of the rare earth element (REE) deposits, on one hand, and their strategic importance, on the other, enhances the necessity of multivariate modeling of these deposits. The wide variations of the grades and their relation with different rock units increase the complexities of the modeling of REEs. In this work, the Gazestan Magnetite-Apatite deposit was investigated and modeled using the statistical and geostatistical methods. Light and heavy REEs in apatite minerals are concentrated in the form of fine monazite inclusions. Using 908 assayed samples, 64 elements including light and heavy REEs from drill cores were analyzed. By performing the necessary pre-processing and stepwise factor analysis, and taking into account the threshold of 0.6 in six stages, a mineralization factor including phosphorus with the highest correlation was obtained. Then using a concentration-number fractal analysis on the mineralization factor, REEs were investigated in various rock units such as magnetite-apatite units. Next, using the sequential Gaussian simulation, the distribution of light, heavy, and total REEs and the mineralization factor in various realizations were obtained. Finally, based on the realizations, the analysis of uncertainty in the deposit was performed. All multivariate studies confirm the spatial structure analysis, simulation and analysis of rock units, and relationship of phosphorus with mineralization.
Mineral Processing
H. Shadi Naghadeh; M. Abdollahy; A. Khodadadi Darban; P. Pourghahramani
Abstract
The Esfordi phosphate concentrate mainly contains fluorapatite, monazite, and xenotime as rare earth element (REE) minerals, accounting for 1.5% of rare earth metals. The monazite and xenotime minerals are refractory and their decomposition is only possible at high temperatures. Thus mechanical activation ...
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The Esfordi phosphate concentrate mainly contains fluorapatite, monazite, and xenotime as rare earth element (REE) minerals, accounting for 1.5% of rare earth metals. The monazite and xenotime minerals are refractory and their decomposition is only possible at high temperatures. Thus mechanical activation was used in the present work for this purpose. After 90 minutes of mechanical activation, the X-ray amorphization phase and the maximum BET surface area were increased to 93.4% and 8.4 m2/g, respectively. The Williamson-Hall plot indicated that the crystallite size was decreased and the lattice strain was increased as a function of the milling intensity. A volume-weighted crystallite size of 64 nm and a lattice strain of 0.9% were achieved from the mechanically activated sample for 90 minutes. The leaching efficiency of REEs with 32% nitric acid at 85 °C was increased from 25% for the initial sample to about 95% for the activated samples. The first stage reaction rate constants for La, Nd, and Ce were increased from 8 × 10-7, 9 × 10-7,and 6 × 10-7 for the initial sample to 1.3 × 10-3, 9 × 10-4, and 7 × 10-4 for the mechanically activated samples at 60 °C, respectively. Also the apparent activation energy for La, Nd, and Ce for the initial sample was found to be about 210, 231, and 229 kJ/mol, which were decreased to 120, 91, and 80 kJ/mol, respectively, after 20 minutes of mechanical activation in an argon atmosphere. The results obtained suggested mechanical activation as an appropriate pre-treatment method for dissolution of REEs from phosphate concentrates containing refractory REE minerals at a lower cost and a higher recovery rate.