Mineral Processing
M. R. Khani; M. Karamoozian
Abstract
In the present work, we investigated and optimized the digestion efficiency, A/S (Al2O3/SiO2 in red mud), and N/S (Na2O/SiO2 in red mud) of mixed bauxite in Iran Alumina Company using the Bayer process. Digestion experiments were carried out in an induction rotary autoclave on a mix of Jajarm, Yazd, ...
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In the present work, we investigated and optimized the digestion efficiency, A/S (Al2O3/SiO2 in red mud), and N/S (Na2O/SiO2 in red mud) of mixed bauxite in Iran Alumina Company using the Bayer process. Digestion experiments were carried out in an induction rotary autoclave on a mix of Jajarm, Yazd, Tash, and Shirin Cheshmeh bauxites. A 4-factor 3-level response surface methodology was applied for the design and analysis of the experiment with the optimization of Na2O concentration, digestion temperature, residence time, and amount of lime addition. Towquadratics and one linear model were derived for the prediction of digestion efficiency, and A/S and N/S responses. The results obtained showed that the optimum amounts for Na2O concentration, temperature, amount of lime addition and residence time were 180 g/L, 275°C, 7.73%, and 50 minutes, respectively, in which the digestion efficiency, A/S, and N/S reached 72.05%, 1.169, and 0.27, respectively. Validation experiment showed that the digestion efficiency, A/S, and N/S were 72.24%, 1.162, and 0.28% respectively, which meant a 2% increase in digestion efficiency and a 0.09 and 0.02 decrease in A/S and N/S, respectively, compared to the current operating condition.
H. Amani; H. Naderi
Abstract
Gallium extraction from Jajarm Bayer process liquor (Jajarm, Iran) was investigated using microemulsions. Also the behavior of aluminum was studied as an impurity. Kelex100 (4-ethyl, 1-methyl, 7-octyl, 8-hydroxyquinoleine), iso-decanol and n-butanol, and kerosene were used as the surfactant, co-surfactant, ...
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Gallium extraction from Jajarm Bayer process liquor (Jajarm, Iran) was investigated using microemulsions. Also the behavior of aluminum was studied as an impurity. Kelex100 (4-ethyl, 1-methyl, 7-octyl, 8-hydroxyquinoleine), iso-decanol and n-butanol, and kerosene were used as the surfactant, co-surfactant, and oil phase, respectively. Ternary phase diagrams were produced using various co-surfactants at different C/S ratios. The results obtained show that Winsor II is the predominant region, and the least area was obtained using iso-decanol at C/S = 4. Using n-butanol or iso-decanol at C/S = 2, 100% of gallium was extracted. The equations of the statistical models for the gallium and aluminum extractions using different co-surfactants were calculated. While the highest gallium extraction (100%) was obtained using n-butanol, due to the high co-extraction of aluminum, the lowest separation and enrichment factors were obtained for this system. The highest separation and enrichment factors were obtained using iso-decanol at C/S = 2. The point with the compositions of XAF = 30, XOF = 20, and XC/S = 50 was found to be a suitable choice, and led to 74% and 14% extractions for gallium and aluminum, respectively. An enrichment factor of 5.28 was obtained.
M. Rezaee Rad; Sh. Shahhoseini; M. Janfada; H. A. Mirzaee; P. Kelidari
Abstract
Low grade diasporic bauxite in the Jajarm mine with an A/S (Al2O3/SiO2) ratio of 2.3 is not usable in the Bayer process at Jajarm Alumina Complex. Due to the severe interlocking effect between the diaspore and aluminosilicate minerals (Chamosite and Kaolinite) and iron-containing minerals in a microcrystal ...
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Low grade diasporic bauxite in the Jajarm mine with an A/S (Al2O3/SiO2) ratio of 2.3 is not usable in the Bayer process at Jajarm Alumina Complex. Due to the severe interlocking effect between the diaspore and aluminosilicate minerals (Chamosite and Kaolinite) and iron-containing minerals in a microcrystal matrix, the thermo-chemical treatment, which is independent from micro-mineralogy, was chosen for bauxite desilication. Five parameters affecting the process and their interactions were investigated using the Taguchi experimental design method. The results obtained showed that there was an interaction between the furnace temperature and the leaching time. Moreover, the optimum values for the parameters involved in the thermo-chemical treatment were determined to be a furnace temperature of 950 °C, a furnace residence time of 90 min, a leaching agent (soda) concentration of 150 g L-1, and a leaching time of 120 min, where the solid content (in leaching) had no effect. Moreover, a model was proposed using the Dx7 software to predict the A/S ratio. The ratio was predicted to be 7.52 at the optimum conditions, whereas in the experiments carried out under the same conditions, it was obtained to be 6.96 ± 0.2, which means a 59% decrease in silica and an increase in the A/S ratio of up to 3 times with 80% weight recovery.