J. Jurković; E. Babajić; T. Muhić – Šarac; M. Kolar; A. Kazlagić
Abstract
Oxidation of sulfide-containing ores is the main cause of Acid Mine Drainage (AMD), which is an environmental problem associated with both the abandoned and active mines. Iron-bearing sulfide minerals can be oxidized and form mine waters with high sulfate content, low pH, high electrical conductivity, ...
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Oxidation of sulfide-containing ores is the main cause of Acid Mine Drainage (AMD), which is an environmental problem associated with both the abandoned and active mines. Iron-bearing sulfide minerals can be oxidized and form mine waters with high sulfate content, low pH, high electrical conductivity, high redox potential, and high concentrations of iron, aluminum, and other heavy metals. In the process of AMD, precipitation of poorly crystalized oxy-hydroxides of iron with a large active surface can occur. On the surface of iron oxy-hydroxide, the precipitated particulate matter, anions, and cations (metals) could be adsorbed. Mine waters can contain a certain amount of precious metals that can also be adsorbed onto an iron particulate matter surface, which is investigated in this research work. In this work, the samples of iron oxy-hydroxide particulate matter at abandoned gold mine waste in Bakovići (Central Bosnia and Herzegovina) are used. Several parameters including pH, water content, particle size distribution, sulfate content, electrical conductivity, redox potential, and amounts of gold, silver, and iron are measured on the selected mine waste samples. The results obtained indicate that significant amounts of gold (average: 6.8 mg/kg) and silver (average: 7.13 mg/kg) are present in the iron precipitate. Adsorption of precious metals onto the iron oxy-hydroxide surface is strongly pH-dependent. At a very low pH value, desorption of precious metals is favorite. Thus, precious metals are only partially adsorbed onto the iron oxy-hydroxide surface.
M. Hosseinzadeh; M. Alizadeh; S. M. Raouf Hosseini
Abstract
In this work, a bench-scale process was developed using mineral-processing methods to recover iron from a placer deposit located in Bardaskan, Khorasan-e-Razavi, Iran. The mineralogical studies were performed by X-ray Diffraction (XRD), X-ray Fluorescence (XRF), Electron Probe Micro-Analyzer (EPMA), ...
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In this work, a bench-scale process was developed using mineral-processing methods to recover iron from a placer deposit located in Bardaskan, Khorasan-e-Razavi, Iran. The mineralogical studies were performed by X-ray Diffraction (XRD), X-ray Fluorescence (XRF), Electron Probe Micro-Analyzer (EPMA), and an optical microscope. These studies indicated that titanomagnetite, magnetite, and hematite were presented in the sample as valuable minerals. In contrast, the gangue minerals were silicates such as pyroxene, plagioclase, quartz, feldspar, calcite, and some secondary minerals. The optimum liberation degree of the iron-containing minerals was obtained to be 75 µm with average Fe and TiO2 contents of 5% and 1%, respectively. The analysis showed that magnetite was the main iron mineral, and most of the hematite was formed due to martitization. Also minor ilmenite contents were found in hematite and magnetite in a blade form. The maximum TiO2 content in the magnetite lattice was 19%, only 8% of which was recovered to the magnetic product. Eventually, an iron concentration flow sheet was developed, which included the removal of a major part of silicates and then iron minerals by a low intensity wet magnetic separator. The final product contained 55, 7.8, and 0.77% of Fe, TiO2, and V2O5, respectively, which can be used for iron production, and V2O5 extraction (as the by-product).