Document Type : Case Study

Authors

1 Tabas Coal Mines Complex (TCMC), Iranian Mines and Mining Industries Development and Renovation Organization (IMIDRO), Iran

2 School of Mining Engineering, College of Engineering, University of Tehran, Tehran, Iran

3 Iran Mineral Processing Research Center (IMPRC), Iran

Abstract

Parvadeh IV and East Parvadeh mines are two main coal-producing zones within the Tabas coalfield, east of Iran. Since studies have shown that C1 and B2 are the most important working seams in the Parvadeh IV and east Parvadeh areas, this research work focuses on these two coal seams. Syngenetic pyrite is available as framboids related to macerals. Decreasing the sulfur content is especially hard when the pyrite particles are fine-grained, finely disseminated, and intergrown with the coal maceral structure. The sulfur content measured in C1 and B2 seams varies from 0.98% to 5.57% and from 0.73% to 5.25%, respectively, with an average of 2.39% and 2.5%. We use a method to predict how coal desulfurized the C1­and B2­seams of Parvadeh IV and C1 seams of east Parvadeh mines in the Tabas coalfield. The results have given new proofs for the presence of pyrite and clay minerals within the coalfield zone, and to identify a method to predict coal desulfurization with conventional processing and cost-effective methods. The coal preparation strategy in MEMRADCO, Parvadeh, and Ehyasepahan coal-cleaning plants not as it expels mineral matter and pyrite but too reduces the content of most inorganic components.

Keywords

[1]. Karayiğit, A.İ., Littke, R., Querol, X., Jones, T., Oskay, R.G., and Christanis, K. (2017). The Miocene coal seams in the Soma Basin (W. Turkey): Insights from coal petrography, mineralogy and geochemistry. International Journal of Coal Geology, 173, 110-128..
[2]. Dai, S., and Finkelman, R.B. (2018). Coal as a promising source of critical elements: Progress and future prospects. International Journal of Coal Geology, 186, 155-164.‏
[3]. Dai, S., Bechtel, A., Eble, C.F., Flores, R. M., French, D., Graham, I.T., and O'Keefe, J.M. (2020). Recognition of peat depositional environments in coal: A review. International Journal of Coal Geology, 219, 103383.
[4]. Duan, P., Wang, W., Liu, X., Sang, S., Ma, M., and Zhang, W. (2019). Differentiation of rare earth elements and yttrium in different size and density fractions of the Reshuihe coal, Yunnan Province, China. International Journal of Coal Geology, 207, 1-11.
[5]. Finkelman, R. B., Dai, S., and French, D. (2019). The importance of minerals in coal as the hosts of chemical elements: A review. International Journal of Coal Geology, 212, 103251.
[6]. Li, D., Tang, Y., Deng, T., Chen, K., Liu, D., and Cheng, F. (2008). Mineralogy of the no. 6 coal from the Qinglong Coalfield, Guizhou Province, China. Energy exploration and exploitation, 26 (6): 347-353.
[7]. Jorjani, E., Rezai, B., Vossoughi, M., and Osanloo, M. (2004). Desulfurization of Tabas coal with microwave irradiation/peroxyacetic acid washing at 25, 55 and 85 C. Fuel, 83 (7-8): 943-949.
[8]. Wheelock, T.D., and Markuszewski, R. (1984). Coal preparation and cleaning. The science and technology of coal and coal utilization, 47-123.
[9]. Singh, P.K., Singh, A.L., Kumar, A., and Singh, M.P. (2013). Control of different pyrite forms on desulfurization of coal with bacteria. Fuel, 106, 876-879.
[10]. Geboy, N.J., Engle, M.A., and Hower, J.C. (2013). Whole-coal versus ash basis in coal geochemistry: a mathematical approach to consistent interpretations. International Journal of Coal Geology, 113, 41-49.
[11]. Xu, N., Finkelman, R.B., Xu, C., and Dai, S. (2020). What do coal geochemistry statistics really mean?. Fuel, 267, 117084.
[12]. Kwiecińska, B., Pusz, S., and Valentine, B.J. (2019). Application of electron microscopy TEM and SEM for analysis of coals, organic-rich shales and carbonaceous matter. International Journal of Coal Geology, 211, 103203.
[13]. Jorjani, E., Chelgani, S.C., and Mesroghli, S. (2007). Prediction of microbial desulfurization of coal using artificial neural networks. Minerals Engineering, 20 (14): 1285-1292.
[14]. Llovet, X., Moy, A., Pinard, P.T., and Fournelle, J.H. (2021). Reprint of: Electron probe microanalysis: A review of recent developments and applications in materials science and engineering. Progress in Materials Science, 120, 100818.
[15]. Ahangaran, D.K., Afzal, P., Yasrebi, A.B., Wetherelt, A., Foster, P.J., and Darestani, R.A. (2011). An evaluation of the quality of metallurgical coking coal seams within the north block of Eastern Parvadeh coal deposit, Tabas, Central Iran. Journal of Mining and Metallurgy A: Mining, 47 (1): 9-24.
[16]. Zamansani, N., Rajabzadeh, M.A., Littke, R., Zieger, L., and Baniasad, A. (2019). Organic petrology and geochemistry of Triassic and Jurassic coals of the Tabas Basin, Northeastern/Central Iran. International Journal of Coal Science & Technology, 6, 354-371.
[17]. NAEIMI, G.N., Saeidi, A., Aghanabati, A., GHOREYSHI, M., and Ghasemi, M.R. (2010). Geohistory Analysis of the Tabas Block (Abdoughi-Parvadeh Basins) as Seen from the Late Triassic through Early Cretaceous Subsidence Curves.
[18]. Moosavirad, S.M., Rasouli, J., Janardhana, M.R., Moghadam, M.R., and Shankara, M. (2013). Petrographic, mineralogy, and geochemistry of coals of Pabedana, Kerman Province, Central Iran. Arabian Journal of Geosciences, 6, 3623-3634.
[19]. Moore, F., and Esmaeili, A. (2012). Mineralogy and geochemistry of the coals from the Karmozd and Kiasar coal mines, Mazandaran province, Iran. International journal of coal geology, 96, 9-21.
[20]. Afzal, P., Alhoseini, S. H., Tokhmechi, B., Ahangaran, D. K., Yasrebi, A. B., Madani, N., and Wetherelt, A. (2014). Outlining of high quality coking coal by concentration–volume fractal model and turning bands simulation in East-Parvadeh coal deposit, Central Iran. International Journal of Coal Geology, 127, 88-99.
[21]. Dai, S., Jiang, Y., Ward, C.R., Gu, L., Seredin, V.V., Liu, H., and Ren, D. (2012). Mineralogical and geochemical compositions of the coal in the Guanbanwusu Mine, Inner Mongolia, China: Further evidence for the existence of an Al (Ga and REE) ore deposit in the Jungar Coalfield. International Journal of Coal Geology, 98, 10-40.
[22]. Kozlov, A., Svishchev, D., Donskoy, I., Shamansky, V., and Ryzhkov, A. (2015). A technique proximate and ultimate analysis of solid fuels and coal tar. Journal of Thermal analysis and Calorimetry, 122, 1213-1220.
[23]. Mishra, V., and Singh, K.N. (2017). Microstructural relation of macerals with mineral matter in coals from Ib valley and Umaria, Son-Mahanadi basin, India. International Journal of Coal Science & Technology, 4, 191-197.
[24]. Singh, M.P., and Singh, P.K. (1995). Mineral Matter in the Lrajmahal Coals: Study Through Incident Light Microscopy and Scanning Electron Micrography. Geological Society of India, 46 (5): 557-564.
[25]. Dai, S., Zhang, W., Ward, C.R., Seredin, V.V., Hower, J.C., Li, X., and Zhou, D. (2013). Mineralogical and geochemical anomalies of late Permian coals from the Fusui Coalfield, Guangxi Province, southern China: influences of terrigenous materials and hydrothermal fluids. International Journal of Coal Geology, 105, 60-84.
[26]. Chou, C. L. (2012). Sulfur in coals: A review of geochemistry and origins. International journal of coal geology, 100, 1-13.
[27]. Rickard, D. (1997). Kinetics of pyrite formation by the H2S oxidation of iron (II) monosulfide in aqueous solutions between 25 and 125 C: The rate equation. Geochimica et Cosmochimica Acta, 61 (1): 115-134.
[28]. Erarslan, C., Örgün, Y., and Balcı, N. (2020). Source and distribution of pyrite and inorganic sulfur isotopes in the Saray and Pınarhisar Coalfields, North Thrace Basin, Turkey. International Journal of Coal Geology, 227, 103533.
[29]. Southam, G., Donald, R., Röstad, A., and Brock, C. (2001). Pyrite discs in coal: Evidence for fossilized bacterial colonies. Geology, 29 (1): 47-50.
[30]. Dai, S., Ren, D., Zhou, Y., Chou, C. L., Wang, X., Zhao, L., and Zhu, X. (2008). Mineralogy and geochemistry of a superhigh-organic-sulfur coal, Yanshan Coalfield, Yunnan, China: Evidence for a volcanic ash component and influence by submarine exhalation. Chemical Geology, 255 (1-2): 182-194.
[31]. Dai, S., Zou, J., Jiang, Y., Ward, C.R., Wang, X., Li, T., and Zhou, D. (2012). Mineralogical and geochemical compositions of the Pennsylvanian coal in the Adaohai Mine, Daqingshan Coalfield, Inner Mongolia, China: Modes of occurrence and origin of diaspore, gorceixite, and ammonian illite. International Journal of Coal Geology, 94, 250-270.
[32]. Goodarzi, F. (2002). Mineralogy, elemental composition and modes of occurrence of elements in Canadian feed-coals. Fuel, 81 (9): 1199-1213.
[33]. Rajabzadeh, M. A., Ghorbani, Z., and Keshavarzi, B. (2016). Chemistry, mineralogy and distribution of selected trace-elements in the Parvadeh coals, Tabas, Iran. Fuel, 174, 216-224.