Document Type : Original Research Paper

Authors

1 Department of Mines and Geotechnology, Institute of Mines, Echahid Cheikh Larbi Tebessi University, 12002, Tebessa, Algeria

2 Mining Laboratory, Institute of Mines, Echahid Cheikh Larbi Tebessi University, 12002, Tebessa, Algeria

3 Department of Mining, University Badji Mokhtar, 23000, Annaba, Algeria

4 Valorization of Mining Resources and Environment Laboratory (LAVAMINE), University Badji Mokhtar, 23000, Annaba, Algeria

5 Department of Natural Resources and Chemical Engineering, Tafila Technical University, Tafila, 66110, Jordan

6 Underground oil, gas and aquifer reservoir laboratory, Department of Earth Sciences, Faculty of Hydrocarbons, Renewable Energies, Earth Sciences and Universe, Kasdi Merbah University, 3000, Ouargla, Algeria

7 Department of Mining and Geology, Abderrahmane Mira University, 06000, Bejaia, Algeria

Abstract

The Djebel Onk region of Algeria faces a significant environmental concern, related to phosphate mining waste. Although these mining tailings contain relatively low quantities of valuable minerals, they still include up to 25% P₂O₅ in the particle size range of 0.25-1 mm (-1-+0.25), suggesting the potential for recovery and reuse. This research, based on the Bir El Ater area, explores the methods to recover phosphate-rich minerals, optimizing their reuse. Two techniques were explored: calcination, a heat treatment altering mineral chemistry, and electrostatic separation, which uses the electrical properties to separate minerals. The black phosphate tailings collected from the curved grids of wet processing were subjected to detailed analysis using Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), and X-Ray Fluorescence (XRF), to examine their mineralogical and chemical properties. The results showed a notable improvement in the P₂O₅ concentration, with electrostatic separation reaching a 30.03% content and an 89% recovery rate, while calcination achieved the 30.91% content with a 91% recovery rate. These results highlight the effectiveness of both methods in recovering phosphate from mining tailings, contributing to a better waste management, a more efficient resource use, and a reduced environmental footprint. They also suggest sustainable recovery pathways, especially for the regions facing water scarcity, where flotation is impractical. With the ability to achieve high recovery rates without chemical inputs, calcination and electrostatic separation stand out as environmentally sustainable options for global phosphate beneficiation.

Keywords

Main Subjects

[1]. Moukannaa, S., Loutou, M., Benzaazoua, M., Vitola, L., Alami, J., & Hakkou, R. (2018). Recycling of phosphate mine tailings for the production of geopolymers. Journal of Cleaner Production, 185, 891–903.
[2]. Corchado-Albelo, J. L., & Alagha, L. (2023). Studies on the enrichment feasibility of rare earth-bearing minerals in mine tailings. Minerals, 13(3), 301.
[3]. Alsafasfeh, A., Alagha, L., Alzidaneen, A., & Nadendla, V. S. S. (2022). Optimization of flotation efficiency of phosphate minerals in mine tailings using polymeric depressants: Experiments and machine learning. Physicochemical Problems of Mineral Processing, 58(4), 150477.
[4]. Birken, I., Bertucci, M., Chappelin, J., & Jorda, E. (2016). Quantification of Impurities, Including Carbonates Speciation for Phosphates Beneficiation by Flotation. Procedia Engineering, 138, 72–84.
[5]. Alsafasfeh, A., Alagha, L., & Al-Hanaktah, A. (2024). The Effect of Methyl Isobutyl Carbinol “MIBC” on the Froth Stability and Flotation Performance of Low-Grade Phosphate Ore. Mining, Metallurgy and Exploration, 41(1), 353–361.
[6]. Abouzeid, A. Z. M. (2008). Physical and thermal treatment of phosphate ores — An overview. International Journal of Mineral Processing, 85(4), 59–84.
[7]. Alsafasfeh, A., Khodakarami, M., Alagha, L., Moats, M., & Molatlhegi, O. (2018). Selective depression of silicates in phosphate flotation using polyacrylamide-grafted nanoparticles. Minerals Engineering, 127, 198–207.
[8]. Bittner, J. D., Gasiorowski, S. A., Hrach, F. J., & Guicherd, H. (2015). ScienceDirect Electrostatic beneficiation of phosphate ores: Review of past work and discussion of an improved separation system.
[9]. Zafar, Z. I., Anwar, M. M., & Pritchard, D. W. (1995). Optimization of thermal beneficiation of a low grade dolomitic phosphate rock. International Journal of Mineral Processing, 43(1–2), 123–131.
[10]. Papalas, T., Antzaras, A. N., & Lemonidou, A. A. (2021). Magnesite-derived MgO promoted with molten salts and limestone as highly-efficient CO2 sorbent. Journal of CO2 Utilization, 53, 101725.
[11]. Bahmani, H., Mostafaei, H., Ghiassi, B., Mostofinejad, D., & Wu, C. (2023). A comparative study of calcium hydroxide, calcium oxide, calcined dolomite, and metasilicate as activators for slag-based HPC. Structures, 58, 105653.
[12]. Sajid, M., Bary, G., Asim, M., Ahmad, R., Irfan Ahamad, M., Alotaibi, H., Rehman, A., Khan, I., & Guoliang, Y. (2022). Synoptic view on P ore beneficiation techniques. Alexandria Engineering Journal, 61(4), 3069–3092.
[13]. Guo, F., & Li, J. (2010). Separation strategies for Jordanian phosphate rock with siliceous and calcareous gangues. International Journal of Mineral Processing, 97(1–4), 74–78.
[14]. Ruan, Y., He, D., & Chi, R. (2019). Review on beneficiation techniques and reagents used for phosphate ores. Minerals, 9(4), 253.
[15]. Derrardjia, N., Nettour, D., Chettibi, M., Chaib, R., Zeghloul, T., Dascalescu, L., & Aouimeur, D. (2024). Study of the feasibility of valorizing phosphate ore by electrostatic separation. Technology Audit and Production Reserves, 2(3(76)), 20–26.
[16]. Anawati, J., & Azimi, G. (2020). Recovery and separation of phosphorus as dicalcium phosphate dihydrate for fertilizer and livestock feed additive production from a low-grade phosphate ore. RSC Advances, 10(63), 38640–38653.
[17]. Dascalescu, L., Zeghloul, T., & Iuga, A. (2016). Electrostatic Separation of Metals and Plastics From Waste Electrical and Electronic Equipment. WEEE Recycling: Research, Development, and Policies, 75–106.
[18]. Safhi, A. el M., Amar, H., El Berdai, Y., El Ghorfi, M., Taha, Y., Hakkou, R., Al-Dahhan, M., & Benzaazoua, M. (2022). Characterizations and potential recovery pathways of phosphate mines waste rocks. Journal of Cleaner Production, 374, 134034.
[19]. Zafar Iqbal Zafar, Anwar, M. M., & Pritchard, D. W. (1996). Innovations in beneficiation technology for low grade phosphate rocks. Nutrient Cycling in Agroecosystems 46(2), 135–151.
[20]. Sobhy, A., & Tao, D. (2014). Innovative RTS Technology for Dry Beneficiation of Phosphate. Procedia Engineering, 83, 111–121.
[21]. Mezghache, H. , Toubal, A. , & Bouima, T. (1980). Typology of phosphate ores in deposits of the Djebel Onk mining basin (eastern Algeria). Phosphorus Research Bulletin, 15, 5–20.
[22]. Kechiched, R., Laouar, R., Bruguier, O., Kocsis, L., Salmi-Laouar, S., Bosch, D., & Larit, H. (2020). Comprehensive REE+ Y and sensitive redox trace elements of Algerian phosphorites (Tébessa, eastern Algeria): A geochemical study and depositional environments tracking. Journal of Geochemical Exploration, 208, 106396.
[23]. Alsafasfeh, A., & Alagha, L. (2017). Recovery of phosphate minerals from plant tailings using direct froth flotation. Minerals, 7(8).
[24]. El Ouardi, E. M., Zeroual, A., Khallouq, K., Darfi, S., & Jedaa, A. (2020). Impact of washing followed by calcination on the quality of bouchane phosphate of Morocco. International Journal of Design and Nature and Ecodynamics, 15(4), 555–563.
[25]. Cao, W., Yi, W., Peng, J., Li, J., & Yin, S. (2022). Recycling of phosphogypsum to prepare gypsum plaster: Effect of calcination temperature. Journal of Building Engineering, 45, 103511.
[26]. Han, B., Zhao, L., Wang, F., Xu, L., Yu, H., Cui, Y., Zhang, J., & Shi, W. (2020). Effect of Calcination Temperature on the Performance of the Ni@SiO2Catalyst in Methane Dry Reforming. Industrial and Engineering Chemistry Research, 59(30), 13370–13379.
[27]. Han, R., Wang, Y., Xing, S., Pang, C., Hao, Y., Song, C., & Liu, Q. (2022). Progress in reducing calcination reaction temperature of Calcium-Looping CO2 capture technology: A critical review. Chemical Engineering Journal, 450, 137952.
[28]. Kim, J. Y., Ellis, N., Lim, C. J., & Grace, J. R. (2020). Effect of calcination/carbonation and oxidation/reduction on attrition of binary solid species in sorption-enhanced chemical looping reforming. Fuel, 271, 117665.
[29]. Abouzeid, A. (2007). Upgrading of phosphate ores-a review. Powder Handling and Processing19(2), 92.