Document Type : Original Research Paper

Authors

Minerals Application Research Centre in the West of Country, Azarshahr, Iran

10.22044/jme.2025.16231.3146

Abstract

The components of low-grade bauxite were 28.4% silica, 34.9% alumina, 16.1% iron oxide as ferric oxide and 11.26% loss on ignition. Due to the high silica content of this type of bauxite, it couldn’t be processed by Bayer method. Therefore, a sintering method with limestone and sodium carbonate was used for selective extraction of alumina. Experimental design was performed by surface response method (RSM) using central composite design. Selected parameters were temperature, soaking time, mole ratio of sodium oxide to alumina, mole ratio of calcium oxide to silica. The maximum amount of extraction of alumina from low-grade Jajarm bauxite by sintering method was 74.2%, which was obtained in the optimal values of the parameters as follows: A temperature of 1157°C, a soaking time of 35 minutes, a mole ratio of alkaline oxide (K2O + Na2O) of 1.25 and a mole ratio of calcium oxide to silica of 1.99. In 31 run experiments, the mixture of materials powder was transferred to an alumina crucible and heated in a muffle furnace at temperatures and soaking times determined by the experimental design. The sintered material was pulverized. The resulting powder was leached by 150 mL of a boiling alkaline solution (20 g/L NaOH + 20g/L Na2CO3) for 30 minutes at a stirring speed of 300rpm. Extracted aluminum from the leaching stage was analyzed by atomic absorption spectrometry.

Keywords

Main Subjects

[1]. Liu, J. (2025). IAI: Global alumina production falls in Nov 2024 m-o-m.
[2]. Zhao, X., Liu, Y., Wang, L., Hua, Y., Cheng, T., Zhang, T., & Zhao, Q.  (2024). Co-Extraction of Aluminum and Silicon and Kinetics Analysis in Carbochlorination Process of Low-Grade Bauxite. Materials (Basel) 17. 10.3390/ma17143613
[3]. Ghaemmaghami, E., Samadzadeh Yazdi, M. R., Darvishi, M. A., Sadati, A. A., & Najafi, A. (2022). Alumina extraction by lime-soda sinter process from low-grade bauxite soil of Semirom mine. Journal of mining and environment 13, 1159-1169
[4]. Bhukte, P. G., Daware, G. T., Masurkar, S. P., Chaddha, M. J., & Agnihotri, A. (2021). Beneficiation of low-grade Bauxite: A case study of Lateritic Bauxite of India. In Innovations in Sustainable Mining: Balancing Environment, Ecology and Economy, pp. 85-98, Springer
[5]. Landek, D., Ćurković, L., Gabelica, I., Kerolli Mustafa, M., & Žmak, I. (2021). Optimization of sintering process of alumina ceramics using response surface methodology. Sustainability 13, 6739
[6]. Kar, M. K., Ӧnal, M. A. R., & Borra, C. R. (2023).Alumina recovery from bauxite residue: A concise review. Resources, Conservation and Recycling 198, 107158
[7]. Toama, H., Al-Ajeel, A.-W., & Jumaah, A. (2018). Studying the Efficiency of Lime-Soda Sinter Process to Extract Alumina from Colored Kaolinite Ores Using Factorial Technique of Design of Experiments. Engineering and Technology Journal 36 Part A, 500-508. 10.30684/etj.36.5A.4
[8]. Smith, P. (2009). The processing of high silica bauxites — Review of existing and potential processes. Hydrometallurgy 98, 162-176.
[9]. Jumaah, A.H. (2017). Extraction of Alumina from Colored Kaolin by Lime-Soda Sinter Process.
[10]. Khodadadi Bordboland, R., Azizi, A., & Khani, M. R. (2024). Extracting alumina from a low-grade (Shale) bauxite ore using a sintering process with lime-soda followed by alkali leaching. Journal of Mining and Environment 15, 1131-1148
[11]. ElDeeb, A. B., Sizyakov, V. M., Brichkin, V. N., & Kurtenkov, R. V. (2020). Effect of sintering temperature on the alumina extraction from kaolin. In Advances in raw material industries for sustainable development goals, pp. 136-145, CRC Press
[12]. Tian, Y., Pan, X., Yu, H., Han, Y., Tu, G., & Bi, S. (2016). An Improved Lime Sinter Process to Produce Al 2 O 3 from Low-Grade Al-Containing Resources: TMS/Light. In, pp. 1-9,
[13]. Hazrati, R., Alizadeh, E., Soltani, S., Keyhanvar, P., & Davaran, S. (2024). Development of a Composite Hydrogel Containing Statistically Optimized PDGF-Loaded Polymeric Nanospheres for Skin Regeneration: In Vitro Evaluation and Stem Cell Differentiation Studies. ACS omega 9, 15114-15133