Document Type : Review Paper

Authors

1 Physical Upgrading Department, Production Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

2 Contracting Department, Contracts and Agreements Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

3 Mineralogy Department, Research Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

4 Remote Sensing Department, Contracts and Agreements Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

5 Studies Department, Contracts and Agreements Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

6 Radioactive Granitic Rocks Department, Research Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

7 Analysis Department, Production Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

8 Research Sector, Nuclear Materials Authority. P.O. Box 530, Maadi, Cairo, Egypt

9 Faculty of Computers and Information, Zagazig University, Zagazig, Egypt

10.22044/jme.2025.16225.3141

Abstract

In response to rising global demand for critical minerals and the need for environmentally responsible resource utilization, this study explores sustainable recovery methods from low-grade placer deposits in the Wadi Rahba area along the Southern Coast of the Red Sea of Egypt. The focus is on the beneficiation of ilmenite and titanite as primary valuable minerals. Twenty-eight samples, including a composite technology sample, were analysed using XRD, SEM-EDX, and ED-XRF techniques. Results indicate that total heavy mineral (THM) content ranges from 4.5% to 17.7%, averaging approximately 10%, with 11% in the composite sample. Identified valuable minerals include titanite, ilmenite, leucoxene, zircon, magnetite, and rutile, alongside high concentrations of heavy silicate minerals such as epidote, pyroxene, and amphiboles. Estimated contents are 0.44 wt.% titanite, 0.15 wt.% ilmenite, and trace amounts of zircon (0.04 wt.%), spessartine (0.01wt.%), and magnetite (0.29 wt.%). To enhance recovery, a combination of gravity separation (Wilfley shaking table) and magnetic separation techniques (LIMS and HIMS) were applied. These methods effectively concentrated titanite and ilmenite, achieving recovery rates of 85.08% and 79%, respectively. The findings highlight the potential for economically viable extraction from low-grade sources using environmentally sustainable physical upgrading techniques.

Keywords

Main Subjects

[1]. Shengo, M., Ilunga, F., & Mambwe Matanda, P. (2024). Linking ores flotation results to the Kinsenda copper deposit mineralogical features: enhancing the recovery of copper retained in flotation tailings. Canadian Metallurgical Quarterly, 1–15. 64(3), 1374–1388.
[2]. Wani, O. B., Khan, S., Shoaib, M., da Costa Gonçalves, C., Chen, Z. Zeng, H., & Bobicki, E. R. (2024). Processing of low-grade ultramafic nickel ores: A critical review. Minerals Engineering, 218, 108976.
[3]. Bulayani, M., Raghupatruni, P., Mamvura, T., & Danha, G. (2024). Exploring Low-Grade Iron Ore Beneficiation Techniques: A Comprehensive Review. Minerals, 14(8), 796.
[4]. Bruckard, W.J., Pownceby, M.I., Smith, L.K., & Sparrow, G.J. (2015). Review of processing conditions for Murray Basin ilmenite concentrates. Mineral Processing and Extractive Metallurgy, 124 (1), 47-63.
[5]. Mudd, G.M., & Jowitt, S.M. (2016). Rare earth elements from heavy mineral sands: assessing the potential of a forgotten resource. Applied Earth Science, 125 (3), 107-113.
[6]. Klein, C., & Philpotts, A. (2013). Earth Materials: Introduction to Mineralogy and Petrology. Cambridge University Press, 536.
[7]. Khedr, M.Z., Zaghloul, H., Takazawa, E., El-Nahas, H., Azer, M.K., & El-Shafei, S.A. (2023). Genesis and evaluation of heavy minerals in black sands: A case study from the southern Eastern Desert of Egypt. Geochemistry, 83 (1), 125945.
[8]. Abdel-Karim, A., Zaid, S.M., Moustafa, M.I., & Barakat, M.G. (2016). Mineralogy, chemistry and radioactivity of the heavy minerals in the black sands, along the northern coast of Egypt. Journal of African Earth Sciences, 123, 10–20.
[9]. Samy, Y., & El-Gohary, A. (2013). Heavy Minerals Pattern and Indices as a Guide for Provenance and Transportation of Beach Sands along the Northern Sinai Coast, Egypt. Journal of Applied Sciences Research, 9 (11), 5656-5664.
[10]. El-Kammar, A.A., Ragab, A.A., & Moustafa, M.I. (2011). Geochemistry of Economic Heavy Minerals from Rosetta Black Sand of Egypt. JAKU: Earth Science, 22(2), 69–97.
[11]. Fawzy, M.M., Abu El Ghar, M.S., Gaafar, I.M., El Shafey, A.M., Diab, M., & Hussein, A.W. (2022a). Diit Quaternary Stream Sediments, Southern Coast of the Red Sea, Egypt: Potential Source of Ilmenite, Magnetite, Zircon, and Other Economic Heavy Minerals. Mining, Metallurgy & Exploration, 39 (2), 655–667.
[12]. Fawzy, M.M., Abu El Ghar, M.S., Gaafar, I.M., El Shafey, A.M., Diab, M., & Hussein, A.W. (2022b). Recovery of valuable heavy minerals via gravity and magnetic separation operations from Diit Quaternary stream sediments, southern coast of the Red Sea, Egypt. Journal of Physics: Conference Series, 2305(1), 1-14.
[13]. Fawzy, M., Bayoumi, M., Shahin, H., Emad, B., El Shafey, A.H., Abdel-Azeem, M., Ismail, A., El-Moghazy, A., & Diab, M. (2024a). Economic heavy minerals in the stream sediments of wadi Shaàb, southern coast of the Red Sea, Egypt; characterization and upgrading for investigation of their potential recovery. Bulletin of the Mineral Research and Exploration, 174 (174), 145-165.
[14]. Fawzy, M., Bayoumi, M., Shahin, H., Emad, B., El Shafey, A.H., Abdel-Azeem, M., Ismail, A., & Diab, M. (2024b). Characterization and beneficiation potential for valuable heavy minerals from Wadi Ibib stream sediments, southern coast of the Red Sea, Egypt. International Journal of Mining and Geo-Engineering, 58 (4), 371-381.
[15]. Titanium Mill Products - Global Strategic Business Report, (2025).  Global Industry Analysts, Inc, 197 Pages. ID: 5141513. http://www.researchandmarkets.com/reports/5141513.
[16]. Laxmi, T., Srikant, S.S., Rao, D.S., & Bhima Rao, R. (2013). Beneficiation studies on recovery and in-depth characterization of ilmenite from red sediments of badlands topography of Ganjam District, Odisha, India. International Journal of Mining Science and Technology, 23(5), 725–731.
[17]. Fawzy, M., Mahdy, N., & Mabrouk, S. (2020). Mineralogical characterization and physical upgrading of radioactive and rare metal minerals from Wadi Al-Baroud granitic pegmatite at the Central Eastern Desert of Egypt. Arabian Journal of Geosciences, 13, 413.
[18]. Fawzy, M.M., Kamar, M.S., & Saleh, G.M. (2021). Physical processing for polymetallic mineralization of Abu Rusheid mylonitic rocks, South Eastern Desert of Egypt. International Review of Applied Sciences and Engineering, 12 (2), 134–146.
[19]. Zhang, S., Rao, M., Xiao, R., You, J., Li, G., & Jiang, T. (2022). Enrichment of Nb and Ti from carbonatite pyrochlore ore via calcining-slaking followed by gravity separation. International Journal of Mining Science and Technology, 32(3), 615–626.
[20]. Zhu, F., Ma, Z., Qiu, K., & Peng, W. (2023). Separation of Ilmenite from Vanadium Titanomagnetite by Combining Magnetic Separation and Flotation Processes. Separations, 10 (2), 95.
[21]. Kim, K., & Jeong, S. (2019). Separation of Monazite from Placer Deposit by Magnetic Separation. Minerals, 9 (3), 149.
[22]. Diab, M., El Ghar, M.A., Gaafar, I.M., El Shafey, A.H.M., Hussein, A.W., & Fawzy, M.M. (2022). Potentiality of Physical Upgrading for Valuable Heavy Minerals from Sermatai Area, Egypt. Journal of Mining and Environment, 13 (1), 15–32.
[23]. Nzeh, N.S., & Popoola, P.A. (2024). Physical beneficiation of heavy minerals – Part 2: A state-of-the-art literature review on magnetic and electrostatic concentration techniques. Heliyon, 10 (11), e32201.
[24]. Gao, Z., Gao, Y., Zhu, Y., Hu, Y., & Sun, W. (2016). Selective Flotation of Calcite from Fluorite: A Novel Reagent Schedule. Minerals, 6 (4), 114.
[25]. Fawzy, M.M. (2018). Surface characterization and froth flotation of fergusonite from Abu Dob pegmatite using a combination of anionic and nonionic collectors. Physicochemical Problems of Mineral Processing, 54 (3), 677–687.
[26]. Fawzy, M.M. (2021). Flotation separation of dravite from phlogopite using a combination of anionic/nonionic surfactants. Physicochemical Problems of Mineral Processing, 57(4), 87–95.
[27]. He, J., Tang, H., Guo, C., Zhu, L., Huang, S., & Yang, B. (2024). Synergist enhancement of effective desilication of graphite ore by rotary triboelectric separation and surface modification. Powder Technology, 444, 119965.
[28]. Yang, B., & He, J. (2025). New insights into selective depression mechanism of Tamarindus indica kernel gum in flotation separation of fluorapatite and calcite. Separation and Purification Technology, 354, 128787.
[29]. Rubio, J., Souza, M.L., & Smith, R.W. (2002). Overview of flotation as a wastewater treatment technique. Minerals Engineering, 15(3), 139–155.
[30]. Thejas, H.K., & Hossiney, N. (2022). A short review on environmental impacts and application of iron ore tailings in development of sustainable eco-friendly bricks. Materials Today: Proceedings, 61, 327–331.
[31]. De Haes, S., Lucas, P., & Haes, S. de. (2024), Environmental impacts of extraction and processing of raw materials for the energy transition. The Hague: PBL Netherlands Environmental Assessment Agency, 40.
[32]. Sabet, A.H. (1972): On the stratigraphy of the basement rocks of Egypt. Ann. Geol. Surv. Egypt, V. II.
[33]. Saleh, G.M., Dawoud, M.I., Shahin, H.A., Khaleal, F.M., & Emad, B.M. (2018). Gabal El Fereyid - Wadi Rahaba area, South Eastern Desert, Egypt: mineralization and spectrometric prospecting. International Journal of Mining Science (IJMS), 4 (2), 1-15.
[34]. El Baraga, M.H. (1992). Geolgical, mineralogical and geochemical studies of the Precamrian rocks around Wadi Rahaba, South Eastern Desert, Egypt. PhD Geol, Faculty of Science, Tanta University, Egypt, 278.
[35]. Abdel Moneim, A.A. (2005). Overview of the geomorphological and hydrogeological characteristics of the Eastern Desert of Egypt. Hydrogeology Journal. 13. 416-425.
[36]. Yousef, A.F., Salem, A.A., Baraka, A.M., & Aglan, O.Sh. (2009). The impact of geological setting on the groundwater occurrences in some wadis in Shalatein-Abu Ramad area, South Eastern Desert, Egypt. European Water, 25 (26), 53-68.
[37]. Shawky, H.A., Said, M.M., El-Aassar, A.M., Kotp, Y.H., & Abdel Mottaleb, M.S.A. (2012). Study the chemical characteristics of groundwater to determine the suitable localities desalination processes in the area between Mersa Alam and Ras Banas, Red Sea Coast Eastern Desert, Egypt. Journal of American Science,8(11), 93-106.  
[38]. Maliva, R.G. (2016). Geostatistical Methods and Applications. In: Aquifer Characterization Techniques. Springer Hydrogeology, 595-617.
[39]. Karwariya, S., Dey, P., Bhogal, N.S., Kanga, S., & Singh, S.K. (2021). A Comparative Study of Interpolation Methods for Mapping Soil Properties: A Case Study of Eastern Part of Madhya Pradesh, India. In: Rai, P.K., Singh, P., Mishra, V.N. (eds) Recent Technologies for Disaster Management and Risk Reduction, 431-449.
[40]. Liu, Z., & Yan, T. (2021). Comparison of Spatial Interpolation Methods Based on ArcGIS. Journal of Physics: Conference Series, 1961 012050.
[41]. Usowicz, B., Lipiec, J., Łukowski, M., & Słomiński, J. (2021). Improvement of Spatial Interpolation of Precipitation Distribution Using Cokriging Incorporating Rain-Gauge and Satellite (SMOS) Soil Moisture Data. Remote Sensing, 13 (5), 1039.
[42]. Boumpoulis, V., Michalopoulou, M., & Depountis, N. (2023). Comparison between Different Spatial Interpolation Methods for the Development of Sediment Distribution Maps in Coastal Areas. Earth Science Informatics, 16, 2069–2087.
[43]. EGSMA (1999). Egyptian geological survey and mining; Geologic Map of Baranis, Quadrangle, Egypt, scale 1:250 0000. Geol. Surv. Cairo, Egypt.