Document Type : Original Research Paper

Authors

1 Faculty of Mining, Petroleum and Geophysics, Shahrood University of Technology, Shahrood, Iran.

2 Research and Development Manager at Jajarm Alumina Company, Jajarm, Iran.

Abstract

Red mud is an important solid tailing with strong alkalinity that is obtained during the extraction of alumina in the Bayer process. The global reserve of red mud is more than 4 billion tons, and its disposal as tailing has always been a serious environmental problem. This tailing is considered as a potential source, due to its high content of valuable metal compounds including iron. In this research work, the extraction of iron in red mud is investigated by the method of reduction roasting. The main influencing factors are also investigated. These methods include reduction in muffle and tube furnace, and temperature, reduction agent, and additive type are as important factors. Reduction roasting of the samples in a tube furnace, with Argon gas and vacuum, a mixture of red mud, graphite, and sodium carbonate at 700–1000 °C results in the formation of Fe3O4. Magnetic measurements indicate that saturation magnetization increases from 0.239 to 38.205 emu/g due to the formation of Fe3O4. Applying the magnetic field intensity of about 1000 Gauss results in the iron recovery of 89.9%.

Keywords

Main Subjects

  • Liu, Y. and Naidu, R. (2014). Hidden values in bauxite residue (red mud): Recovery of metals. Waste management, 34(12), 2662-2673.
  • Davris, P., Balomenos, E., Panias, D., and Paspaliaris, I. (2016). Leaching rare earth elements from bauxite residue using brønsted acidic ionic liquids. In Rare earths industry (pp. 183-197). Elsevier.
  • Sinha, S., Sinha, M. K., and Pandey, B. D. (2014). Extraction of lanthanum and cerium from Indian red mud. International Journal of Mineral Processing, 127, 70-73.
  • Liu, W., Yang, J., and Xiao, B. (2009). Review on treatment and utilization of bauxite residues in China. International Journal of Mineral Processing, 93(3-4), 220-231.
  • Zhu, D. Q., Chun, T. J., Pan, J., and He, Z. (2012). Recovery of iron from high-iron red mud by reduction roasting with adding sodium salt. Journal of Iron and Steel Research International, 19(8), 1-5.
  • Rao, M., Zhuang, J., Li, G., Zeng, J., and Jiang, T. (2016). Iron recovery from red mud by reduction roasting-magnetic separation. Light Metals 2013, 125-130.
  • Chun, T., Li, D., Di, Z., Long, H., Tang, L., Li, F., and Li, Y. (2017). Recovery of iron from red mud by high-temperature reduction of carbon-bearing briquettes. Journal of the Southern African Institute of Mining and Metallurgy, 117(4), 361-364.
  • Ponomar, V. P. (2018). Synthesis and magnetic properties of magnetite prepared by chemical reduction from hematite of various particle sizes. Journal of Alloys and Compounds, 741, 28-34.
  • Agrawal, S., Rayapudi, V., and Dhawan, N. (2018). Extraction of iron values from red mud. Materials Today: Proceedings, 5(9), 17064-17072.
  • Sadangi, J. K., Das, S. P., Tripathy, A., & Biswal, S. K. (2018). Investigation into recovery of iron values from red mud dumps. Separation science and technology, 53(14), 2186-2191.
  • Li, P., Liu, Z., Yan, H., and He, Y. (2019, April). Recover iron from bauxite residue (Red Mud). In IOP Conference Series: Earth and Environmental Science (Vol. 252, No. 4, p. 042037). IOP Publishing.
  • Mombelli, D., Barella, S., Gruttadauria, A., and Mapelli, C. (2019). Iron recovery from bauxite tailings red mud by thermal reduction with blast furnace sludge. Applied Sciences, 9(22), 4902.
  • Jin, J., Liu, X., Yuan, S., Gao, P., Li, Y., Zhang, H., and Meng, X. (2021). Innovative utilization of red mud through co-roasting with coal gangue for separation of iron and aluminum minerals. Journal of Industrial and Engineering Chemistry, 98, 298-307.
  • Wan, J., Chen, T., Zhou, X., Luo, Y., Liu, W., and Lu, Q. (2021). Efficient improvement for the direct reduction of high-iron red mud by co-reduction with high-manganese iron ore. Minerals Engineering, 174, 107024.
  • Liu, X., Han, Y., He, F., Gao, P., and Yuan, S. (2021). Characteristic, hazard and iron recovery technology of red mud-A critical review. Journal of Hazardous Materials, 420, 126542.