Sina Ghasemi; Sima Mohammadnejad; Mohammad Reza Khalesi
Abstract
The adsorption of gold and copper cyanide complexes on the activated carbon is investigated using the Density Functional Theory (DFT). In order to represent the activated carbon, two fullerene-like model (presenting structural defect sites) and a simple graphene layer containing different functional ...
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The adsorption of gold and copper cyanide complexes on the activated carbon is investigated using the Density Functional Theory (DFT). In order to represent the activated carbon, two fullerene-like model (presenting structural defect sites) and a simple graphene layer containing different functional groups (presenting chemical active sites) are employed. The structural defect sites show a much lower adsorption tendency toward all the cyano complexes comparing to the chemical active sites. The interaction energy for all of the complexes with structural defect sites (concave) is very low. However, the graphene layer with unsaturated active sites displays the highest level of interaction almost for all the complexes except Cu(CN)4-3. The effect of oxygen functional groups on the graphite edges shows a crucial role in the selectivity of gold adsorption over copper complexes. It has increased adsorption energy for Cu(CN)2- in the presence of OH and COOH, and has decreased adsorption energy for Au(CN)2- by OH and increased by COOH. The study results elucidate the lower selectivity for adsorption of gold over copper cyanides by high oxygen content activated carbon. The energy levels of the HOMO and LUMO orbitals show adsorption of unpaired cyanide anions on the activated carbon surface occurs by electron transfer from the complex to the adsorbent and adsorption onto the activated carbon edges by transferring electrons from the absorbent to the complex. The result has clearly demonstrated that the functional groups increase the adsorption tendency for both the gold (only COOH) and copper complexes (OH and COOH) but deteriorate the selectivity of gold over copper cyanides.
M. Mohammadkhani; M. Abdollahy; M. R. Khalesi
Abstract
Copper oxide minerals such as malachite do not respond well to the traditional copper sulfide collectors, and require alternative flotation schemes. In many copper ore mines, significant copper oxide minerals, especially malachite, are associated with sulfide minerals. Considering that xanthates are ...
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Copper oxide minerals such as malachite do not respond well to the traditional copper sulfide collectors, and require alternative flotation schemes. In many copper ore mines, significant copper oxide minerals, especially malachite, are associated with sulfide minerals. Considering that xanthates are most widely used in the flotation of sulfide minerals as well as copper sulfide minerals and, hydroxamate has shown a good selectivity for copper oxide minerals. Use of the synergistic effect of xanthate and hydroxamate can be an effective way to increase the flotation efficiency of copper oxide minerals along with sulfide minerals. In this work, we investigate the individual interactions of potassium amyl xanthate (PAX) and potassium alkyl hydroxamate (HXM) with the natural malachite and explore their synergistic effects on the malachite flotation. The results of solubility of malachite in collector solutions, changes in the malachite surface potential, adsorption kinetics, adsorption densities, dynamic contact angles, FT-IR analyses, and small-scale flotations, are discussed. The results obtained demonstrate that PAX and HXM are chemically co-adsorbed on the malachite surface, and the amount of PAX adsorbed on the malachite surface is considerably increased in the mixed PAX/HXM systems because of the co-adsorption mechanism. The flotation results confirm that the mixed PAX/HXM exhibit a superior flotation performance of malachite compared to the individual system of PAX or HXM. Based on these results, the mixed PAX/HXM exhibit a remarkable synergism effect on malachite surface hydrophobicity.
Mineral Processing
Y. Kianinia; M. R. Khalesi; M. Abdollahy; A. Khodadadi Darban
Abstract
Processing of gold ores with high sulfide minerals is problematic as they consume cyanide and reduce gold leaching. Optimization of gold leaching and cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, their leaching kinetics, and speciation of cyanide complexes that ...
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Processing of gold ores with high sulfide minerals is problematic as they consume cyanide and reduce gold leaching. Optimization of gold leaching and cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, their leaching kinetics, and speciation of cyanide complexes that consume the free cyanide and compete with gold. In this paper, a physico-chemical approach is presented to estimate the liberation and exposure of cyanicides to the leaching solution, and then prediction of the speciation of all possible related species in the solution. The results obtained show that this methodology not only could successfully estimate the gold leaching and cyanide consumption based on the mineralogical data with a lower number of parameters compared to existing empirical models, but also offers the prediction of formation of all the possible complexes that could be used for optimization purposes.
Mineral Processing
M. Mohseni; M. Abdollahy; R. Poursalehi; M. R. Khalesi
Abstract
The reactivity of the protonated and hydroxylated sphalerite (1 1 0) surface with xanthate was simulated using the density functional theory (DFT). The difference between the energy of the lowest unoccupied molecular orbital of the sphalerite surface and the energy of the highest occupied molecular orbital ...
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The reactivity of the protonated and hydroxylated sphalerite (1 1 0) surface with xanthate was simulated using the density functional theory (DFT). The difference between the energy of the lowest unoccupied molecular orbital of the sphalerite surface and the energy of the highest occupied molecular orbital of xanthate ( was used to compare the reaction capability of xanthate with fresh and functionalized surfaces. The Mulliken atomic charge analysis was used to provide an in-depth insight into the effects of –H+ and –OH- groups on the reactivity of Zn atoms at the sphalerite surface. The values for different systems showed that the protonated surfaces exposed a higher reactivity with xanthate than the fresh and hydroxylated surfaces. The results of the Mulliken atomic charge analysis demonstrated that after the formation of –H+ and –OH- contained groups on the sphalerite surface, the surface atoms found a new charge due to the reduction and oxidation mechanism. In addition, the results obtained revealed that the electrophilicity of Zn atoms after the ion adsorption could be considered as a key factor in the reactivity of the sphalerite surface with xanthate. The DFT-based calculations also showed that different alkyl groups of xanthate had no significant influence on the reactivity of their head groups. The findings of this research work provided insights into the reactions of the sphalerite surface with xanthate.
Mineral Processing
A. Eskanlou; M. R. Khalesi; M. Abdollahy; M. Hemmati Chegeni
Abstract
The success of flotation operation depends upon the thriving interactions of chemical and physical variables. In this work, the effects of particle size, bubble size, and collector dosage on the bubble loading in a continuous flotation column were investigated. In other words, this work was mainly concerned ...
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The success of flotation operation depends upon the thriving interactions of chemical and physical variables. In this work, the effects of particle size, bubble size, and collector dosage on the bubble loading in a continuous flotation column were investigated. In other words, this work was mainly concerned with the evaluation of the true flotation response to the changes in the operating variables in column flotation. Two bubble sizes of 0.8 and 1.8 mm, three size fractions of 63-106, 106-150, and 150-300 μm, and three different dosages of dodecylamine, as the collector, were tested. According to the results obtained, the particle size fraction of 106-150 μm had the maximum bubble loading for bubble diameter of 1.8 mm, while the particle size of 63-106 μm had the maximum bubble loading for bubble diameter of 0.8 mm. It was also shown that increasing the bubble diameter from 0.8 to 1.8 mm increased the bubble loading in all the particle size fractions and collector dosages. However, the mass loading of air bubbles was strongly related to the collector dosage (contact angle), especially for coarse particles. The amount of collector dosage had an upper limit due to the clustering event, which significantly affected the bubble loading. The clustering was found to be more important in the presence of small particles due to a higher number of particles attached to the bubble surface. It was shown that such interactions of variables of true flotation could reasonably be monitored by the bubble loading measurement.
Mineral Processing
F. Basirifar; M.R. Khalesi; M. Ramezanizadeh; M. Abdollahy; A. Hajizadeh
Abstract
Partition curves are widely used to determine the spiral separator efficiency. In this work, the partition curves were used in order to investigate the particle transportation to concentrate and tailing streams. Simulation of fine particle removal using the size-by-size partition curves showed that the ...
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Partition curves are widely used to determine the spiral separator efficiency. In this work, the partition curves were used in order to investigate the particle transportation to concentrate and tailing streams. Simulation of fine particle removal using the size-by-size partition curves showed that the recovery of gangue particles to concentrate can decrease 8.7%. It also showed that the recovery of valuable particles would increase by 6.5% and reaches 90%. Therefore, pilot-scale tests were conducted to verify the simulations. After removal of fine particles from the feed of spiral separator and treating the removed materials with high-intensity magnetic separator, total mass recovery, iron recovery, and iron grade increased from 71%, 85%, and 54% to 80%, 91%, and 56%, respectively.
