Elahe Ghaemmaghami; Mohamad Reza Samadzadeh Yazdi; Mohammad Amin Darvishi; Ali akbar Sadati; Abbas Najafi
Abstract
As the mass ratio of alumina to silica (A/S ratio) in bauxite decreases, the cost of alumina production by the Bayer process sharply increases. With the increasingly fierce competition in the alumina industry and the gradual reduction in bauxite grade, when the A/S ratio drops to 3-4, the Bayer process ...
Read More
As the mass ratio of alumina to silica (A/S ratio) in bauxite decreases, the cost of alumina production by the Bayer process sharply increases. With the increasingly fierce competition in the alumina industry and the gradual reduction in bauxite grade, when the A/S ratio drops to 3-4, the Bayer process is challenging to meet the market competition and production requirements. In such cases, the alumina production by sintering method has a vast development prospect and application potential for low-grade bauxite ores. The low A/S ratio and the high iron oxide content are the difficulties in the alumina production by the sintering process. This work adopts the lime-soda sinter process for extracting alumina from bauxite samples (A/S ratio = 1.34 and 20.80% Fe2O3) of the Semirom mine in Iran. The effects of sintering parameters are investigated. The maximum alumina extraction (88%) was obtained by a CaO/SiO2 molar ratio of 1.2, Na2O/Al2O3 molar ratio of 0.9, and sintering temperature at 1250 °C for 80 min. Also 83% of alumina is extracted by decreasing the N/A ratio to 0.66, to decrease the sodium carbonate consumption for a more economical process. The sintered materials are leached with sodium carbonate solution, and aluminum hydroxide [Al(OH)3] is precipitated. Finally, pure alumina (Al2O3) is obtained with a purity of 98 % after calcination at 1200 °C for 2 hours.
M. R. Samadzadeh Yazdi; M. Abdollahi; S. M. Mousavi; A. Khodadadi Darban
Abstract
Although bioleaching of chalcopyrite by thermophilic microorganisms enhances the rate of copper recovery, a high temperature accelerates iron precipitation as jarosite, which can bring many operational problems in the industrial processes. In this research work, the bioleaching of chalcopyrite concentrate ...
Read More
Although bioleaching of chalcopyrite by thermophilic microorganisms enhances the rate of copper recovery, a high temperature accelerates iron precipitation as jarosite, which can bring many operational problems in the industrial processes. In this research work, the bioleaching of chalcopyrite concentrate by the thermophilic Acidianus brierleyi was studied, and the microbial growth, copper dissolution, iron oxidation, and jarosite precipitation were monitored in different initial pH (pHi) values. Bacterial growth was greatly affected by pHi. While the bacterial growth was delayed for 11 days with a pHi value of 0.8, this delay was reduced to nearly one day for a pHi value of 1.2. Two stages of copper recovery were observed during all the tests. A high pHi value caused a fast bacterial growth in the first stage and severe jarosite precipitation in the later days causing a sharp decline in the bacterial population and copper leaching rate. The copper recoveries after 11 days were 25%, 78%, 84%, 70%, 56%, and 39% for the pHi values of 0.8, 1.0, 1.2, 1.3, 1.5, and 1.7, respectively. Sulfur and jarosite were the main residues of the bioleaching tests. It was revealed that the drastic effect of jarosite precipitation on the microbial growth and copper recovery was mainly caused by the ferric iron depletion from solution rather than passivation of the chalcopyrite surface. A slow precipitation of crystalline jarosite did not cause a passive chalcopyrite surface. The mechanisms of chalcopyrite bioleaching were discussed.
