Mineral Processing
Mohammadreza Shahbazi; Hadi Abdollahi; Sied Ziaeddin Shafaei; Ziaeddin Pourkarimi; Sajjad Jannesar Malakooti; Ehsan Ebrahimi
Abstract
Tabas coal possesses favorable plastometric properties that make it suitable for use in metallurgical industries as coking coal. However, its high sulfur content, which stands at approximately 2%, poses a significant environmental pollution risk. Additionally, reducing ash content to below 10% is a critical ...
Read More
Tabas coal possesses favorable plastometric properties that make it suitable for use in metallurgical industries as coking coal. However, its high sulfur content, which stands at approximately 2%, poses a significant environmental pollution risk. Additionally, reducing ash content to below 10% is a critical objective of this study to prevent a decline in coal's thermal efficiency in the metallurgical industries. This research work investigates the removal of sulfur and ash from Tabas coal samples using the biological methods including bioflotation and bioleaching. Initially, a combination of mesophilic bacteria including Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans, and Leptosprillium ferrooxidans were employed in the bioflotation method to detain pyrite sulfur in the Tabas coal samples. The highest reduction percentages of pyrite sulfur and ash were equal to 62% and 54.18%, respectively. In the next stage, bioleaching experiments were conducted, the effect of the test time, percentage of bacteria by volume, percentage of coal solids, and absence of bacteria on the amount of sulfur and ash removal was investigated. The test time emerged as the most critical factor. The best sulfur removal was achieved using bioleaching, with a maximum removal of 72.43%, observed for the PE coal sample. Bioflotation also achieved significant sulfur removal, with a maximum removal of 61% observed for the same sample. On the other hand, the best ash removal was achieved using bioflotation, with a maximum removal of 68.98% observed for the PE coal sample, and a maximum removal of 69.34% observed for the B4B2 coal sample using bioleaching. Finally, this research work conducted a comparison of biological methods to determine the amount of sulfur and ash reduction achieved. The results showed that both bioleaching and bioflotation were effective for coal desulfurization and ash removal, with bioleaching performing slightly better for sulfur removal and bioflotation performing slightly better for ash removal.
M. R. Samadzadeh Yazdi; M. Abdollahi; S. M. Mousavi; A. Khodadadi Darban
Abstract
Although bioleaching of chalcopyrite by thermophilic microorganisms enhances the rate of copper recovery, a high temperature accelerates iron precipitation as jarosite, which can bring many operational problems in the industrial processes. In this research work, the bioleaching of chalcopyrite concentrate ...
Read More
Although bioleaching of chalcopyrite by thermophilic microorganisms enhances the rate of copper recovery, a high temperature accelerates iron precipitation as jarosite, which can bring many operational problems in the industrial processes. In this research work, the bioleaching of chalcopyrite concentrate by the thermophilic Acidianus brierleyi was studied, and the microbial growth, copper dissolution, iron oxidation, and jarosite precipitation were monitored in different initial pH (pHi) values. Bacterial growth was greatly affected by pHi. While the bacterial growth was delayed for 11 days with a pHi value of 0.8, this delay was reduced to nearly one day for a pHi value of 1.2. Two stages of copper recovery were observed during all the tests. A high pHi value caused a fast bacterial growth in the first stage and severe jarosite precipitation in the later days causing a sharp decline in the bacterial population and copper leaching rate. The copper recoveries after 11 days were 25%, 78%, 84%, 70%, 56%, and 39% for the pHi values of 0.8, 1.0, 1.2, 1.3, 1.5, and 1.7, respectively. Sulfur and jarosite were the main residues of the bioleaching tests. It was revealed that the drastic effect of jarosite precipitation on the microbial growth and copper recovery was mainly caused by the ferric iron depletion from solution rather than passivation of the chalcopyrite surface. A slow precipitation of crystalline jarosite did not cause a passive chalcopyrite surface. The mechanisms of chalcopyrite bioleaching were discussed.
Mineral Processing
M. Naderi; Seyed Z. Shafaie; M. Karamoozian; Sh. Gharanjik
Abstract
In this work, the parameters affecting the recovery of copper from the low-grade sulfide minerals of Sarcheshmeh Copper Mine were studied. A low-grade sulfide ore was used with a copper grade of 0.25%, which was about 28% of the mineral oxide, and the sulfide minerals made up the rest. Much more sulfide ...
Read More
In this work, the parameters affecting the recovery of copper from the low-grade sulfide minerals of Sarcheshmeh Copper Mine were studied. A low-grade sulfide ore was used with a copper grade of 0.25%, which was about 28% of the mineral oxide, and the sulfide minerals made up the rest. Much more sulfide minerals were found to be pyrite and most of the gangue minerals were quartz, anorthite, biotite, and muscovite. In order to investigate, simultaneously, the solids (10 to 20%) and acidity (1.5 to 2.5) and shaking (110 to 150 rpm), the separation of bacteria from Sarcheshmeh Copper Mine was carried out. After adjustment of the sample, bio-leaching tests were performed in accordance with the pattern defined by the software DX7 in shaking flasks, and the Cu recovery was modeled and optimized using the response surface methodology. The influential parameters were comprehensively studied. The central composite design methodology was used as the design matrix to predict the optimal level of these parameters. Then the model equation was optimized. The results obtained showed that increasing solids (from 10 to 20%) was bad for bacteria. The highest copper recovery was equivalent to 69.91%, obtained after 21 days at 35 degrees using the Acidi Thiobacillus Ferrooxidans bacteria and a K9 medium with a pulp density of 10% and pH 1.5.
