Mineral Processing
Kwang Sok Jong; Chang Il Kim; Kum Chon Jang; Song Chol Kim; Hyon Hui Jang
Abstract
In this study, the effects of various reagents-sodium carbonate and sodium hydroxide as pH regulators, calcium lignosulfonic acid as depressant, and combined sodium oleate and amide as collector on the flotation of apatite ore were investigated using flotation experiments, and adsorption mechanism of ...
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In this study, the effects of various reagents-sodium carbonate and sodium hydroxide as pH regulators, calcium lignosulfonic acid as depressant, and combined sodium oleate and amide as collector on the flotation of apatite ore were investigated using flotation experiments, and adsorption mechanism of collector on apatite surface were evaluated using quantum mechanical simulations. The flotation experiments showed that the addition of 4 kg/t sodium carbonate and 1.5 kg/t sodium hydroxide as pH regulators, 3 kg/t calcium lignosulfonic acid as depressant and 60 g/t combined sodium oleic acid and oleamide (acid number of collector; 105 mgKOH/g) as collector exhibited excellent collecting ability for apatite. From low-grade apatite ore with P2O5 7.05%, a concentrate with P2O5 31.42% was obtained with 81.08% recovery in rougher flotation. Compared with the simulation results for the interaction energy between apatite {001} surface and collectors, and the relative concentration of collector on apatite {001} surface, adsorption strength has following order; combined sodium oleic acid and oleamide > sodium oleic acid > oleamide. From the simulation results on the equilibrium configuration of the collector with the fluorapatite {001} surface in the liquid environment, it was revealed that the two atoms (N and H) of the oleamide can form a strong bidentate conformation, and O atom in the C-O group and that in -C=O group of oleic acid anion can bond with the Ca atom on the surface {001} to form monodentate conformation.
Mineral Processing
Alireza Javadi
Abstract
The main and economic mineral of antimony is stibnite or antimony sulfide, and the research and processes in the world are based on it, and oxide minerals are not considered among the economic and important reserves of antimony due to the difficulty of processing and the lack of optimal efficiency of ...
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The main and economic mineral of antimony is stibnite or antimony sulfide, and the research and processes in the world are based on it, and oxide minerals are not considered among the economic and important reserves of antimony due to the difficulty of processing and the lack of optimal efficiency of the flotation method. On the other hand, taking into account that a large part of the antimony reserve of Sefidabeh is made up of low-grade oxidized ore; this research on the method of economic extraction and the possibility of recovering this type of reserve will be important due to the strategic nature of antimony metal. According to the experiments conducted in this research, the effective parameters for flotation include: pH, collector concentration, activator concentration, depressant concentration, activator type, and humic acid concentration. DX7 software was used for statistical modeling of experiments. Based on the above parameters, the design of the experiment was carried out using a partial factorial method and finally the number of 16 experiments was determined for the effect of the above factors on the grade and weight recovery of the sample. Antimony ore flotation with a grade of 4.32% was carried out in a two-stage method. In this method, in the first stage, flotation of antimony sulfur (stibnite, Sb2S3) was performed at a specific pH by adding the activator of copper sulfate or lead nitrate and the depressant together, potassium amyl xanthate collector and MIBC. In the second stage of flotation, the tailings of the first stage of flotation for antimony oxides were treated with a sodium oleate collector (with determined concentrations) at a specific pH by adding copper sulfate or lead nitrate activator, sodium oleate collector and humic acid and MIBC frother agent. The interaction between pH and activator concentration (BD) has a direct effect on the amount of concentrated antimony, with an increase in pH from 6 to 8 antimony when using an activator concentration of 300 g/t, and a decrease when using an activator concentration of 500 g/t. Flotation was done. In the best conditions, with two-stage flotation of antimony, 68.99% recovery and 13.32 grade were obtained.
Mineral Processing
A.R. Javadi
Abstract
Carnallite, with the chemical formula KMgCl3.6H2O, is a mineral that was first discovered in the Urals Mountains in Russia. The reverse flotation has been established for carnallite processing in the current decades, and the alkyl morpholine collector is used for the removal of NaCl from carnallite using ...
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Carnallite, with the chemical formula KMgCl3.6H2O, is a mineral that was first discovered in the Urals Mountains in Russia. The reverse flotation has been established for carnallite processing in the current decades, and the alkyl morpholine collector is used for the removal of NaCl from carnallite using the reverse flotation. The carnallite processing method involves reverse flotation with the dodecyl morpholine collector, and then centrifugation and cold crystallization. In this research work, kimiaflot 619, as a new collector, is synthesized, and the bench-scale flotation shows that kimiaflot 619 reveals a better selectivity and affinity for the NaCl crystals at an acidic pH with a less collector dosages–only 1/2 of the Armoflot 619 collector. The flotation results indicate that the NaCl grade in carnallite concentrated by Armoflot 619 (200 g/t) is 2.86%, while the NaCl grade in carnallite concentrated by kimiaflot 619collector (100 g/t) is 2.75%. The frother’s stability of the Armoflot 619 collector after flotation is very high and uncontrollable, while kimiaflot 619 has solved this problem, and it is completely controllable.
