Mineral Processing
Alireza Javadi
Abstract
The main and economic mineral of antimony is stibnite or antimony sulfide, and the research and processes in the world are based on it, and oxide minerals are not considered among the economic and important reserves of antimony due to the difficulty of processing and the lack of optimal efficiency of ...
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The main and economic mineral of antimony is stibnite or antimony sulfide, and the research and processes in the world are based on it, and oxide minerals are not considered among the economic and important reserves of antimony due to the difficulty of processing and the lack of optimal efficiency of the flotation method. On the other hand, taking into account that a large part of the antimony reserve of Sefidabeh is made up of low-grade oxidized ore; this research on the method of economic extraction and the possibility of recovering this type of reserve will be important due to the strategic nature of antimony metal. According to the experiments conducted in this research, the effective parameters for flotation include: pH, collector concentration, activator concentration, depressant concentration, activator type, and humic acid concentration. DX7 software was used for statistical modeling of experiments. Based on the above parameters, the design of the experiment was carried out using a partial factorial method and finally the number of 16 experiments was determined for the effect of the above factors on the grade and weight recovery of the sample. Antimony ore flotation with a grade of 4.32% was carried out in a two-stage method. In this method, in the first stage, flotation of antimony sulfur (stibnite, Sb2S3) was performed at a specific pH by adding the activator of copper sulfate or lead nitrate and the depressant together, potassium amyl xanthate collector and MIBC. In the second stage of flotation, the tailings of the first stage of flotation for antimony oxides were treated with a sodium oleate collector (with determined concentrations) at a specific pH by adding copper sulfate or lead nitrate activator, sodium oleate collector and humic acid and MIBC frother agent. The interaction between pH and activator concentration (BD) has a direct effect on the amount of concentrated antimony, with an increase in pH from 6 to 8 antimony when using an activator concentration of 300 g/t, and a decrease when using an activator concentration of 500 g/t. Flotation was done. In the best conditions, with two-stage flotation of antimony, 68.99% recovery and 13.32 grade were obtained.
Mineral Processing
A.R. Javadi
Abstract
Carnallite, with the chemical formula KMgCl3.6H2O, is a mineral that was first discovered in the Urals Mountains in Russia. The reverse flotation has been established for carnallite processing in the current decades, and the alkyl morpholine collector is used for the removal of NaCl from carnallite using ...
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Carnallite, with the chemical formula KMgCl3.6H2O, is a mineral that was first discovered in the Urals Mountains in Russia. The reverse flotation has been established for carnallite processing in the current decades, and the alkyl morpholine collector is used for the removal of NaCl from carnallite using the reverse flotation. The carnallite processing method involves reverse flotation with the dodecyl morpholine collector, and then centrifugation and cold crystallization. In this research work, kimiaflot 619, as a new collector, is synthesized, and the bench-scale flotation shows that kimiaflot 619 reveals a better selectivity and affinity for the NaCl crystals at an acidic pH with a less collector dosages–only 1/2 of the Armoflot 619 collector. The flotation results indicate that the NaCl grade in carnallite concentrated by Armoflot 619 (200 g/t) is 2.86%, while the NaCl grade in carnallite concentrated by kimiaflot 619collector (100 g/t) is 2.75%. The frother’s stability of the Armoflot 619 collector after flotation is very high and uncontrollable, while kimiaflot 619 has solved this problem, and it is completely controllable.
Mineral Processing
B. Nemati Akhgar; A. Fathzade; B. Golizadeh; S. Hajilou
Abstract
The flotation circuit in Sungun copper plant consists of two column flotation cells as cleaner, having fixed-spargers system. To achieve the expected aims in flotation step, there are serious operational challenges such as: fast choking of the static mixers, boiling problem, burping phenomena and pulp ...
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The flotation circuit in Sungun copper plant consists of two column flotation cells as cleaner, having fixed-spargers system. To achieve the expected aims in flotation step, there are serious operational challenges such as: fast choking of the static mixers, boiling problem, burping phenomena and pulp overflow to concentrate lander, maintenance and control problems. An attempt was exerted by implementing new helical static mixer in one of cleaner cells instead of old elliptical type to overcome the challenges. The changes resulted in proper performance of the column whereas burping phenomena due to choking was eliminated, finer bubbles were produced, and the boiling and overflow problems were solved. Also, the static mixers life time increased to 7 months in helical column cells from one month in elliptical column cells. In addition to 40% air consumption reduction and 20% solid percent increase in final product, the grade of Cu and Mo increased by helical static mixer replacement up to about 18.7% from 16.8% (11%) and to 511.1 ppm from 263 ppm (94%) in the cleaner step, respectively. Recovery of Cu and Mo were increased about 1.5% and 0.2%, respectively. Finally, the results proved the effectiveness of finer bubble generation on grade improvement is depend on minerals hydrophobicity as Mo grade increased more than Cu.
Mineral Processing
K. Barani; M. Azghadi; M. R. Azadi; A. Karrech
Abstract
The influence of microwave treatment on the surface roughness, hydrophobicity, and chemical composition of galena was studied. The pure galena specimens and purified galena concentrate were used in this work. A conventional multi-modal oven (with a frequency of 2.45 GHz and a maximum power of 900 W) ...
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The influence of microwave treatment on the surface roughness, hydrophobicity, and chemical composition of galena was studied. The pure galena specimens and purified galena concentrate were used in this work. A conventional multi-modal oven (with a frequency of 2.45 GHz and a maximum power of 900 W) was used to conduct the experiments. The results obtained from the atomic-force microscopy analysis showed that the surface roughness of galena decreased after the microwave radiation. The results also showed that the surface hydrophobicity of galena increased with increase in the duration of the microwave radiation, which was in good agreement with the micro-flotation mass recovery results. The increased surface hydrophobicity may be attributed to the decreased surface roughness by microwave radiation or formation of sulfur on the surface. The results of the SEM/EDS analyses indicated that after microwave radiation, the amount of S increased, whereas Pb decreased on the surface of galena, indicating that the average atomic number of the galena surface changed due to microwave treatment.
Mineral Processing
S. Khoshjavan; K. Moshashaei; B. Rezai
Abstract
In this research work, the effects of flotation parameters on coking coal flotation combustible material recovery (CMR) were studied by the artificial neural networks (ANNs) method. The input parameters of the network were the pulp solid weight content, pH, collector dosage, frother dosage, conditioning ...
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In this research work, the effects of flotation parameters on coking coal flotation combustible material recovery (CMR) were studied by the artificial neural networks (ANNs) method. The input parameters of the network were the pulp solid weight content, pH, collector dosage, frother dosage, conditioning time, flotation retention time, feed ash content, and rotor rotation speed. In order to select the most efficient model for this work, the outputs of different models were compared with each other. A five-layer ANN was found to be optimum with the architecture of 8, 15, 10, and 5 neurons in the input layer, and the first hidden, second hidden, and third hidden layers, respectively, as well one neurons in the output layer. In this work, the training, testing, validating, and data square correlation coefficients (R2) were achieved to be 0.995, 0.999, 0.999, and 0.998, respectively. The sensitivity analysis showed that the rotor speed and the solid weight content had the highest and lowest effects on CMR, respectively. It was verified that the predicted ANN values coincided very well with the experimental results.
Mineral Processing
M. Salehfard; M. Noaparast; Seyed Z. Shafaei; H. Abdollahi
Abstract
A lead-zinc carbonate ore sample containing 2.5% Pb and 9.39% Zn was used in this research work. The sample was prepared from the Darreh-Zanjir mine located in the Yazd province (Iran). Influences of the influential factors on flotation of smithsonite and cerussite were investigated. Among the different ...
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A lead-zinc carbonate ore sample containing 2.5% Pb and 9.39% Zn was used in this research work. The sample was prepared from the Darreh-Zanjir mine located in the Yazd province (Iran). Influences of the influential factors on flotation of smithsonite and cerussite were investigated. Among the different parameters involved, dosages of the dispersant, depressants, sulfidizing agent, and collectors de-sliming prior to lead or zinc flotation were essential for the effective recovery and grade of the Zn and Pb flotation concentrates. In addition, the anionic, cationic, and mixed (cationic/anionic) collectors were employed for flotation of smithsonite. The results of reverse and cumulative flotation of both Zn and Pb were relatively low in comparison with the direct process without depressant. Flotation of smithsonite using mixed collectors (Armac C+KAX) showed promising results. Also dosages of chemicals in the cleaning stage for the Zn and Pb concentrates were optimized, and finally, after the cleaner stage for both lead and zinc, a cerussite concentrate with Pb grade and recovery of 49.82% and 60.06%, respectively, and smithsonite concentrate with Zn grade and recovery of 35.47% and 68.56%, respectively, were obtained under the optimal conditions. Furthermore, kinetics of Zn and Pb oxide mineral flotations in the rougher and cleaner stages were studied, which showed that some kinetics models, especially the classical first-order model, could predict the flotation behaviour of the Zn and Pb oxide minerals.
Mineral Processing
S. G. Ozkan
Abstract
Ultrasound can be used both simultaneously or as a pretreatment technique for flotation to produce higher combustible recoveries, higher heat values, and lower ash data from raw hard coals. The recent research works have indicated that modifying coal surfaces, especially physical surface cleaning with ...
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Ultrasound can be used both simultaneously or as a pretreatment technique for flotation to produce higher combustible recoveries, higher heat values, and lower ash data from raw hard coals. The recent research works have indicated that modifying coal surfaces, especially physical surface cleaning with the help of the cavitation process created by power ultrasound at certain frequency and time intervals, might cause significant changes in flotation responses by a thorough adsorption of reagents on coal surfaces. When power ultrasound is applied to a coal slurry that makes the bubbles to collapse near a coal surface, a high-speed jet of liquid is driven into the particles, and this jet may deposit enormous energy densities at the site of impact. The simultaneous ultrasonic treatment also causes significant changes in local temperatures and pressures within the slurry containing coal and a certain number of reagents at variable dosages during flotation. This treatment improves the effectiveness of reagent molecules at coal surfaces and interfaces due to their more uniform distribution in the pulp and also enhancement of the activity of the reagents used. This paper reviews the results of the recent studies and the possible mechanism of simultaneous ultrasound-assisted coal flotation.
Mineral Processing
S. Nazari; Seyed Ziaedin Shafaei; M. Gharabaghi; R. Ahmadi; B. Shahbazi
Abstract
In this work, the effects of the types of frother (MIBC, pine oil, and A65) and operational parameters (impeller speed and air flow rate) on the flotation of quartz coarse particles was investigated using nano bubbles (NBs). Quartz particles of the size of -425+106 mm and three types of frother were ...
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In this work, the effects of the types of frother (MIBC, pine oil, and A65) and operational parameters (impeller speed and air flow rate) on the flotation of quartz coarse particles was investigated using nano bubbles (NBs). Quartz particles of the size of -425+106 mm and three types of frother were used for the flotation experiments. Also the impeller speed was 600 to 1300 rpm, and the air flow rates were 30 and 60 L/h. In the absence of NBs, the maximum recovery was achieved with the pine oil frother, an impeller speed of 1000 rpm, and an air flow rate of 60 L/h. In the presence of NBs, the maximum recovery was achieved using pine oil at an impeller speed of 900 rpm and an air flow rate of 30 L/h. However, increasing the recovery in the presence of NBs, compared to the absence of NBs for MIBC, was more than the other two frothers, and the recovery using this frother to increase up to 25% but using pine oil, the recovery increased up to 23%. The lowest recovery in the presence of NBs was obtained using A65. Also the use of NBs increased recovery in all the three fractions compared to the absence of NBs but the presence of NBs increased the recovery of particles with size of -212+106 mm more than the particle size in the ranges of -300+212 and -425+300 mm.
M. Shamsi; M. Noparast; Seyyed Z. Shafaie; M. Gharabaghi; S. Aslani
Abstract
Copper smelting slags are hard materials. Therefore,to recover their copper by flotation method, grinding should be carried out to obtain optimal particle size. Copper smelting slags in the Bardeskan district, with work index of 16.24 kwh/st, were grinded for 65 minutes to reach an acceptable degree ...
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Copper smelting slags are hard materials. Therefore,to recover their copper by flotation method, grinding should be carried out to obtain optimal particle size. Copper smelting slags in the Bardeskan district, with work index of 16.24 kwh/st, were grinded for 65 minutes to reach an acceptable degree of freedom for the flotation tests, with particle size of 80%, smaller than 70 μm. With this grinding time, degree of freedom for copper-bearing minerals was achieved 85-90%. The floatation method performed and the procedure used for the optimization of the effective parameters were described in this paper. The results obtained for the flotation tests, carried out at the optimal conditions after grinding the slags (with a grinding time of65 minutes), showed 62.23% of copper recovery, while, by flotation of copper slags at optimal conditions after increasing the grinding time to 85 minutes (d80 = 48µ), the Cu recovery was increased to 79.89%.
