R. Aram; M. Abdollahi; P. Pourghahramani; M. Mohseni; A. Khodadadi Darban
Abstract
In this research work, the solubility of sphalerite concentrate due to mechanical activation in planetary ball mill in both the wet and dry modes is investigated, and the parameters of mean particle size, BET specific surface area, SEM, and XRD are analyzed. The results of the particle size analysis ...
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In this research work, the solubility of sphalerite concentrate due to mechanical activation in planetary ball mill in both the wet and dry modes is investigated, and the parameters of mean particle size, BET specific surface area, SEM, and XRD are analyzed. The results of the particle size analysis and BET specific surface area show that the size of particles for the non-activated sample decrease from 51 to 30 microns but the BET specific surface area increase from 0.17 m2/g to 1.03 m2/g for the residue and feed samples. In the wet and dry mode mechanical activation, the mean particle size and BET specific surface area in the residue samples are reduced relative to the leaching feed. The results of the micro-structure characterization also show that the amorphization of the residue compared to the leaching feed increases in both modes of mechanical activation. The crystallite size and lattice strain of the activated samples in the residue increase and decrease compared to the leaching feed, respectively.
Z. Piervandi; A. Khodadadi Darban; Seyed M. Mousavi; M. Abdollahi; Gh.R. Asadollahfardi; K. Akbari Noghabi
Abstract
Indigenous acidophilic bacteria separated from mine-waste can be used in return for the addition of the reagents like sulfuric acid. Among the tailings bacteria, Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans are of the most-studied ones for the bioleaching and bioremediation of elements. ...
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Indigenous acidophilic bacteria separated from mine-waste can be used in return for the addition of the reagents like sulfuric acid. Among the tailings bacteria, Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans are of the most-studied ones for the bioleaching and bioremediation of elements. In this work, the isolation and characterization of the mentioned bacteria are studied by a proposed biochemical protocol. The sequential cultivation of the soil bacteria in a series of liquid media and solid cult
M. R. Samadzadeh Yazdi; M. Abdollahi; S. M. Mousavi; A. Khodadadi Darban
Abstract
Although bioleaching of chalcopyrite by thermophilic microorganisms enhances the rate of copper recovery, a high temperature accelerates iron precipitation as jarosite, which can bring many operational problems in the industrial processes. In this research work, the bioleaching of chalcopyrite concentrate ...
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Although bioleaching of chalcopyrite by thermophilic microorganisms enhances the rate of copper recovery, a high temperature accelerates iron precipitation as jarosite, which can bring many operational problems in the industrial processes. In this research work, the bioleaching of chalcopyrite concentrate by the thermophilic Acidianus brierleyi was studied, and the microbial growth, copper dissolution, iron oxidation, and jarosite precipitation were monitored in different initial pH (pHi) values. Bacterial growth was greatly affected by pHi. While the bacterial growth was delayed for 11 days with a pHi value of 0.8, this delay was reduced to nearly one day for a pHi value of 1.2. Two stages of copper recovery were observed during all the tests. A high pHi value caused a fast bacterial growth in the first stage and severe jarosite precipitation in the later days causing a sharp decline in the bacterial population and copper leaching rate. The copper recoveries after 11 days were 25%, 78%, 84%, 70%, 56%, and 39% for the pHi values of 0.8, 1.0, 1.2, 1.3, 1.5, and 1.7, respectively. Sulfur and jarosite were the main residues of the bioleaching tests. It was revealed that the drastic effect of jarosite precipitation on the microbial growth and copper recovery was mainly caused by the ferric iron depletion from solution rather than passivation of the chalcopyrite surface. A slow precipitation of crystalline jarosite did not cause a passive chalcopyrite surface. The mechanisms of chalcopyrite bioleaching were discussed.
Mineral Processing
P. Karimi; A. Khodadadi Darban; Z. Mansourpour
Abstract
Low-intensity magnetic separators are widely used in the research works and the industry. Advancement in the magnetic separation techniques has led to an expansion in the application of this method in different fields such as enrichment of magnetic mineral, wastewater treatment, and medicine transfer ...
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Low-intensity magnetic separators are widely used in the research works and the industry. Advancement in the magnetic separation techniques has led to an expansion in the application of this method in different fields such as enrichment of magnetic mineral, wastewater treatment, and medicine transfer in the human body. In the mineral processing industry, the main application of wet magnetic separation is via drum separators. The design of this separator is based on drum rotation inside a tank media, where a permanent magnet placed inside the drum as an angle form produces a magnetic field. In the present work, the magnetic variables involved (magnetic flux density, intensity of magnetic field, and gradient of magnetic field intensity) were simulated in the drum wet low-intensity magnetic separator using the finite element method and a COMSOL Multiphysics simulator; these variables were further validated through the measured data. A comparison between the simulation and laboratory measurements (of the magnetic field) showed that the mean value of the simulation error in 94 points in 2 sections was equal to 9.6%. Furthermore, the maximum simulation error in the middle of the magnets, as the most important part of the magnetic field distribution in the process of magnetic separation, was in the 6th direction and equal to 7.8%. Therefore, the performed simulation can be applied as a first step to design and construct more advanced magnetics separators.
Mineral Processing
H. Shadi Naghadeh; M. Abdollahy; A. Khodadadi Darban; P. Pourghahramani
Abstract
The Esfordi phosphate concentrate mainly contains fluorapatite, monazite, and xenotime as rare earth element (REE) minerals, accounting for 1.5% of rare earth metals. The monazite and xenotime minerals are refractory and their decomposition is only possible at high temperatures. Thus mechanical activation ...
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The Esfordi phosphate concentrate mainly contains fluorapatite, monazite, and xenotime as rare earth element (REE) minerals, accounting for 1.5% of rare earth metals. The monazite and xenotime minerals are refractory and their decomposition is only possible at high temperatures. Thus mechanical activation was used in the present work for this purpose. After 90 minutes of mechanical activation, the X-ray amorphization phase and the maximum BET surface area were increased to 93.4% and 8.4 m2/g, respectively. The Williamson-Hall plot indicated that the crystallite size was decreased and the lattice strain was increased as a function of the milling intensity. A volume-weighted crystallite size of 64 nm and a lattice strain of 0.9% were achieved from the mechanically activated sample for 90 minutes. The leaching efficiency of REEs with 32% nitric acid at 85 °C was increased from 25% for the initial sample to about 95% for the activated samples. The first stage reaction rate constants for La, Nd, and Ce were increased from 8 × 10-7, 9 × 10-7,and 6 × 10-7 for the initial sample to 1.3 × 10-3, 9 × 10-4, and 7 × 10-4 for the mechanically activated samples at 60 °C, respectively. Also the apparent activation energy for La, Nd, and Ce for the initial sample was found to be about 210, 231, and 229 kJ/mol, which were decreased to 120, 91, and 80 kJ/mol, respectively, after 20 minutes of mechanical activation in an argon atmosphere. The results obtained suggested mechanical activation as an appropriate pre-treatment method for dissolution of REEs from phosphate concentrates containing refractory REE minerals at a lower cost and a higher recovery rate.
Mineral Processing
Y. Kianinia; M. R. Khalesi; M. Abdollahy; A. Khodadadi Darban
Abstract
Processing of gold ores with high sulfide minerals is problematic as they consume cyanide and reduce gold leaching. Optimization of gold leaching and cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, their leaching kinetics, and speciation of cyanide complexes that ...
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Processing of gold ores with high sulfide minerals is problematic as they consume cyanide and reduce gold leaching. Optimization of gold leaching and cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, their leaching kinetics, and speciation of cyanide complexes that consume the free cyanide and compete with gold. In this paper, a physico-chemical approach is presented to estimate the liberation and exposure of cyanicides to the leaching solution, and then prediction of the speciation of all possible related species in the solution. The results obtained show that this methodology not only could successfully estimate the gold leaching and cyanide consumption based on the mineralogical data with a lower number of parameters compared to existing empirical models, but also offers the prediction of formation of all the possible complexes that could be used for optimization purposes.
M.R. Shahverdi; A. Khodadadi Darban; M. Abdollahy; Yadollah Yamini
Abstract
Flotation is a common process in sulfide ore beneficiation. Due to the restrictions and lack of access to high-quality water sources for industrial purposes, recycled water plays an important role in the flotation processes. Due to the existence of various organic and inorganic substances in the process, ...
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Flotation is a common process in sulfide ore beneficiation. Due to the restrictions and lack of access to high-quality water sources for industrial purposes, recycled water plays an important role in the flotation processes. Due to the existence of various organic and inorganic substances in the process, water influences the flotation performance. In this work, the effect of accumulation of sulfate ion in processed water on galena flotation was investigated. Flotation experiments using processed water without sulfate ion led to a concentrate containing 40.7% of lead and a maximum recovery of 58.9%. The presence of higher sulfate ion levels (2000 M) in processed water caused a significant decrease in the grade and recovery of the lead concentrate. With 2000 mg/L of sulfate ion, the grade and recovery of lead decreased from 40.7 to 24.3% and from 58.9 to 32.1 %, respectively. Thermodynamic calculations showed that when the sulfate ion concentration was increased from 300 to 2000 ppm, it was more likely that lead sulfate (solid) was formed. With increase in the xanthate ion concentration from 10-6 to 10-4 M, could be substituted by . On the basis of the results obtained, it was concluded that in order to reduce the negative effects of sulfate ion accumulation in water and increase the efficiency of the galena flotation process, higher dosages of xanthates should be added to the system.
M Mohammadiun; B. Dahrazma; Seyed F. Saghravani; A. Khodadadi Darban
Abstract
Use of nanotechnology has proven to be a promising approach toward remediation of all phases of environment. The aim of this work is to investigate the effects of different parameters on using iron III oxide nanoparticles in a continuous flow configuration for the removal of Cd2+ ionsfrom contaminated ...
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Use of nanotechnology has proven to be a promising approach toward remediation of all phases of environment. The aim of this work is to investigate the effects of different parameters on using iron III oxide nanoparticles in a continuous flow configuration for the removal of Cd2+ ionsfrom contaminated soils. Also selective sequential extraction tests are carried out to evaluate the nanoparticle tendency to remove cadmium from different fractions of soils. In order to achieve this goal, a specific flow rate of a nanoparticle solution was passed through a soil sample in a column with 3 cm diameter and 4 cm height. Up to 100% of cadmium removal was achieved by providing a nano-fluid concentration of 500 ppm, pH of 6.5, treatment duration of 24 hours, and flow rate of 0.5 mL/min. Evaluation of the results obtained showed that the tendency of the iron oxide nanoparticles to remove cadmium from different fractions of contaminated soil was in the order of exchangeable > carbonates > oxides and hydroxides > organic matter > residual. The results obtained from this work can be used to develop an appropriate remediation protocol for contaminated soils.
M. Hasani; Seyed M. J. Koleini; A. Khodadadi
Abstract
In the present work, the extraction of zinc from a sphalerite concentrate using sodium nitrate as an oxidant in a sulfuric acid solution was investigated. The effective parameters such as the temperature, sulfuric acid and sodium nitrite concentrations, stirring speed, particle size, and solid/liquid ...
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In the present work, the extraction of zinc from a sphalerite concentrate using sodium nitrate as an oxidant in a sulfuric acid solution was investigated. The effective parameters such as the temperature, sulfuric acid and sodium nitrite concentrations, stirring speed, particle size, and solid/liquid (S/L) ratio were analyzed. The dissolution rate increased with increase in the sulfuric acid and sodium nitrite concentrations and temperature but decreased with increase in the particle size and S/L ratio. Moreover, the stirring speed had a significant effect on the leaching rate. Under the optimum conditions, 74.11% of zinc was obtained. The kinetic data obtained was analyzed by the shrinking core model (SCM). A new SCM variant captured the kinetic data more appropriately. Based on this model, the activities of the reactants control the diffusion but the two concentrations affect the second order reaction rate or diffusion in both directions. At 75 ˚C, the R2 values in the surface chemical reactions and diffusion were 0.78 and 0.89, respectively. Using the new model, however, the R2 value 0.989 was obtained. The reaction orders with respect to [H2SO4], [NaNO3], S/L ratio, and particle size were 1.603, 1.093, ‒0.9156, and ‒2.177, respectively. The activation energy for the dissolution was 29.23 kJ/mol.
Saeed Alishahi; Ahmad Darban; Mahmood Abdollahi
Abstract
Since a high toxicity of cyanide which use as a reagent in the gold processing plant, thiosulfate has been recognized as a environmental friendly reagent for leaching of gold from ore. After gold leaching process it's important for recovery of gold from solution using adsorption or extraction methods, ...
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Since a high toxicity of cyanide which use as a reagent in the gold processing plant, thiosulfate has been recognized as a environmental friendly reagent for leaching of gold from ore. After gold leaching process it's important for recovery of gold from solution using adsorption or extraction methods, One of these methods is activated carbon.The loading of gold from industrial thiosulfate solution that obtained from Zarshuran gold plant-Takab-Iran, onto activated carbon have been investigated. The affecting variables of the adsorption of gold on the carbon included, temperature, concentration of gold, size of activated carbon, pH and the ratio of amount of activated carbon to the volume of solution. The results have shown that at low concentration of gold, effective loading can be achieved at pH 10.5. The size of activated carbon has a significant effect on the loading of gold. In this research the recovery of gold on activated carbon has been predicted using artificial neural network. For this purpose temperature, pH, the proportion of solution volume to weight of activated carbon, gold concentration and time of adsorption were taken as input parameters, whereas, the recovery of gold on activated carbon from thiosulfate solution was considered as an output parameter. The network with LMBP algorithm with two hidden layer were used and the topology 5-4-13-1 showed the best ability for prediction.Moreover sensitive analyze were indicated parameters pH and temperature have substantial influence on adsorption.
Mohammad Reza Samadzadeh Yazdi; Mohammad Reza Tavakoli Mohammadi; Ahmad Khodadadi
Abstract
Arsenic is one of the heavy metals and nearly all its compounds, especially organic compounds, are toxic. The wide spectrum of diseases caused by this element has led to evaluation of the toxicity of different arsenic species and identification of the major natural and anthropogenic pollution sources ...
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Arsenic is one of the heavy metals and nearly all its compounds, especially organic compounds, are toxic. The wide spectrum of diseases caused by this element has led to evaluation of the toxicity of different arsenic species and identification of the major natural and anthropogenic pollution sources of it in the nature. Mining activities are among the main sources of anthropogenic pollution of soil and water by arsenic. The purpose of this study was geochemical modeling of different arsenic species in the wastewater of the tailings dam of Mouteh Gold processing plant in Iran to evaluate the effect of pH and temperature on the stability of these components. Modeling was done using MINTEQ software. The results showed that arsenic species at different pH values under study were H3AsO3, H2AsO3- and HAsO32-, and their actual concentration in the plant wastewater were negligible. MINTEQ software introduced H3AsO4, H2AsO4-, HAsO42- and AsO43- as arsenic V species at different pH values, of which HAsO42- and AsO43- were the main components of arsenic in plant wastewater. Given the low toxicity of arsenic V species and their easier elimination relative to arsenic III species, in the current conditions, the plant wastewater is in a good status in terms of arsenic pollution. Also temperature changes have little effect on the concentration of various arsenic species in the wastewater.
