Areeba Qazi; Kanwarpreet Singh
Abstract
The rock mass classification system is utilized to categorize rocks, and has been used in engineering projects and stability investigations. It focuses on the parameters of rock mass and engineering applications, which include tunnels, slopes, foundations, etc. Rock mass classification is valuable in ...
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The rock mass classification system is utilized to categorize rocks, and has been used in engineering projects and stability investigations. It focuses on the parameters of rock mass and engineering applications, which include tunnels, slopes, foundations, etc. Rock mass classification is valuable in the areas where the collection of samples and yielding of observation is difficult. With the advancement in technology, various machine-based model algorithms have been used, i.e., ANN and MLR in rock mass classification from prior few years. In the present work, the rock mass classification has been discussed, i.e., rock load, stand up time, RQD, RMR, Q, GSI, SMR, and RMi along with their applications. Considering all the parameters, it is concluded that for slope stability in a poor rock condition, the applicability of GSI is sufficient when compared with RMR. GSI also provides a highly accurate valuation of geo-mechanical properties, making it a valuable tool for the engineers and geologists. Also, the RMR values obtained from the ANN model provide better results for tunnels when compared with MLR and the conventional method. The ARMR classification of Slate, Shale, Quartz Schist, Gneiss, and Calcschist at 5 different locations of the world were 51-54, 66-70, 57-60, 35, 65-70, respectively. The range for slate and shale was found to be moderately anisotropic, while quartz schist, gneiss, and calcschist were found to be slightly anisotropic and highly anisotropic.
Rock Mechanics
A. Alikhani; M. Taheri Moghadder; H. Mohammadi
Abstract
One of the most effective parameters in economics of open-pit mines is the pit slope angle, so that the slope angle more than the optimum value increases the probability of a large failure in the pit wall and the slope angle less than the optimum value leads to increasing stripping ratio and reducing ...
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One of the most effective parameters in economics of open-pit mines is the pit slope angle, so that the slope angle more than the optimum value increases the probability of a large failure in the pit wall and the slope angle less than the optimum value leads to increasing stripping ratio and reducing net present value of mine. Therefore, in this paper, considering the limit equilibrium methods of modified Bishop and modified Janbu and numerical models of the slope stability analysis, the effect of overall slope angle on the Economics of open pit mines was investigated. In addition, it was shown that selecting the overall slope angle less than the optimum value leads to reducing the depth of open-pit mining (the ultimate pit depth) and consequently, reducing the net present value of mine. Finally, in homogenous and Isotropic media, the results of Bishop and Janbu and numerical modeling are close together.
Rock Mechanics
Avinash Bhardwaj; Ajay Bhardwaj; Madhusudan Sarda; Namrata Bichewar
Abstract
Narmada valley development authority proposed a scheme under which 12.6 cumecs of water from the Hathani river (Tributary of Narmada) will be lifted to irrigate the command area. At the pumping station lies near Alirajpur, Madhya Pradesh, India, there was a need to protect the slope on both side as water ...
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Narmada valley development authority proposed a scheme under which 12.6 cumecs of water from the Hathani river (Tributary of Narmada) will be lifted to irrigate the command area. At the pumping station lies near Alirajpur, Madhya Pradesh, India, there was a need to protect the slope on both side as water thrust from the upstream side may lead to failure of the slope. This paper presents the stability analysis of the slope using GEO5 software. It was observed that the terrain at the site was a mixture of soil and rocks. The unit weight of the rock and backfill soil observed was 21 kN/m3 and 18 kN/m3. Using numerous techniques factor of safety was calculated for the particular slope and it was observed that a suitable mitigation measure needs to be provided to prevent the failure of the slope. The inclusion of a gabion retaining wall increased the slope's safety factor significantly. The proposed mitigation measure was executed at the site, and the completed wall has not shown any damage till date. The analysis of the slope's stability results, as well as its construction of the gabion retaining wall recommended as a protective measure, are presented in this work.
S. E. Mirsalari; M. Fatehi Marji; J. Gholamnejad; M. Najafi
Abstract
Analysis of the stresses, displacements, and horizontal strains of the ground subsidence due to underground excavation in rocks can be accomplished by means of a hybridized higher order indirect boundary element/finite difference (BE/FD) formulation. A semi-infinite displacement discontinuity field is ...
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Analysis of the stresses, displacements, and horizontal strains of the ground subsidence due to underground excavation in rocks can be accomplished by means of a hybridized higher order indirect boundary element/finite difference (BE/FD) formulation. A semi-infinite displacement discontinuity field is discretized (numerically) using the cubic displacement discontinuity elements (i.e. each higher order element is divided into four sub-elements bearing a cubic variation in the displacement discontinuities). Then the classical finite difference formulation (i.e. the backward, central, and forward finite difference formulations) is hybridized using the boundary element formulation, enabling us to obtain the nodal tangential stresses and horizontal strains along the elements. Several example problems are solved numerically, and the results obtained are then compared with their corresponding results available in the literature. These comparisons show the effectiveness and validness of the proposed method. A classical practical problem is also used to verify the applicability of the hybridized method.
Mineral Processing
M. Ghanbari; H. Naderi; M. Torabi
Abstract
Solvent extraction of copper from the copper leach solution obtained from the ammoniacal carbonate leaching of the Sarcheshmeh copper concentrate was carried out, and the performance of CP-150, LIX984N, and Kelex100 as well as the effects of different parameters involved were investigated. According ...
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Solvent extraction of copper from the copper leach solution obtained from the ammoniacal carbonate leaching of the Sarcheshmeh copper concentrate was carried out, and the performance of CP-150, LIX984N, and Kelex100 as well as the effects of different parameters involved were investigated. According to the results obtained, the extraction kinetics of all the three extractants was fast. High concentrations (7.5%, V/V) of CP-150 and Kelex100 were required to completely extract copper, while only 1% of LIX984N was sufficient. Addition of hexane to the diluent decreased the capability of CP-150 to extract copper, while it showed less effects on LIX984N and Kelex100. A desirable stripping of copper from the loaded organic phase could be obtained using H2SO4 solution.
M. Dehvedar; P. Moarefvand; A.R. Kiyani; A. R. Mansouri
Abstract
Inadequate hole cleaning can lead to many problems in horizontal and directional wells. In this work, we tried to investigate the cutting transport phenomenon by an experimental directional drilling simulator, considering the differences between the operational and experimental conditions. The inclination, ...
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Inadequate hole cleaning can lead to many problems in horizontal and directional wells. In this work, we tried to investigate the cutting transport phenomenon by an experimental directional drilling simulator, considering the differences between the operational and experimental conditions. The inclination, fluid type (water, foam, viscous, and dense), rotary speed (0 and 110 rpm), nozzle bit size (4, 6, and 8 mm), and stabilizer location (8 and 95 cm from the bit) were included in the tests as the main parameters. It could be concluded that the nozzle size and the stabilizer position influenced the hole cleaning time. In vertical wells, by decreasing the nozzle size from 8 mm to 4 mm, the hole cleaning time was increased. The presence of stabilizer reduced the cleaning time, and optimizing the stabilizer position reduced the probability of cutting bed formation in all inclinations. Finally, a third polynomial equation was fitted between the dimensionless mass and the dimensionless cleaning time.
M. Taghvaeenejad; M.R. Shayestefar; P. Moarefvand
Abstract
At different stages of mining, we always face a degree of uncertainty. Some of these uncertainties, such as the amount of reserve and grade of the deposit, are due to the inherent changes in the deposit and directly affect the technical and economic indicators of the deposit. On the other hand, the heavy ...
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At different stages of mining, we always face a degree of uncertainty. Some of these uncertainties, such as the amount of reserve and grade of the deposit, are due to the inherent changes in the deposit and directly affect the technical and economic indicators of the deposit. On the other hand, the heavy costs of the exploration sector often limit the amount of exploratory information, which necessitates the use of accurate estimation methods. In this work,we examines the modeling and estimation results using the conventional and simple kriging methods and the effects of the diverse indicators used in the classification of mineral storages or the parameters defining these indices. 127 exploratory boreholes with an average depth of 95 m are used to build the block model of the deposit in the Data Mine software. After the statistical studies, the 3D variographic studies are performed in order to identify the anisotropy of the region. A grade block model is constructed using the optimal variogram parameters.Then, using various methods to estimate the block model uncertainty including the kriging estimation variance, block error estimation, kriging efficiency and slope of regression, the mineral reserves are classified according to the JORC standard code. Based on different cut-off grades, the tonnage and average grade are calculated and plotted. In this work, an innovative quantitative method based on the grade-number and grade-volume fractal model is used to indicate the classification of mineral reserves. The use of fractal patterns due to the amplitude of the variation is greater and more important than the standard and provides us with a better understanding of the deposit changes per block. The existence of a minimal difference between the use of the standard and fractal patterns in the slope of the regression method indicates less error and is a proof of more reliable results.
Rock Mechanics
M. M. Samieinejad; N. Hosseini; K. Ahangari
Abstract
In order to analyze the slope stability in open-pit mines, the structural parameters of rock mass such as persistence and spatial orientation of discontinuities are characterized through field surveys, which involve spending high costs and times as well as posing high risks of rock toppling and rock ...
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In order to analyze the slope stability in open-pit mines, the structural parameters of rock mass such as persistence and spatial orientation of discontinuities are characterized through field surveys, which involve spending high costs and times as well as posing high risks of rock toppling and rock fall. In the present work, a new application of terrestrial digital photogrammetry is introduced for characterizing the rock mass structural parameters through preparing photogrammetry images from open-pit walls and building stereomodels. The data extracted from processing the stereo-model generations using photogrammetry images with different focal distances are highly consistent with the data collected through field surveys. However, it must be noted that the weather conditions, natural lighting angle, and applied observation scale may considerably affect the results obtained from stereomodel processing. Nevertheless, by taking into account the parameters such as time, cost, and full access to the required data, this new method can effectively be used in the estimation of rock mass structural parameters for analysis of steep slopes in open pits.
E. Emami Meybodi; Syed Kh. Hussain; M. Fatehi Marji; V. Rasouli
Abstract
In this work, the machine learning prediction models are used in order to evaluate the influence of rock macro-parameters (uniaxial compressive strength, tensile strength, and deformation modulus) on the rock fracture toughness related to the micro-parameters of rock. Four different types of machine ...
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In this work, the machine learning prediction models are used in order to evaluate the influence of rock macro-parameters (uniaxial compressive strength, tensile strength, and deformation modulus) on the rock fracture toughness related to the micro-parameters of rock. Four different types of machine learning methods, i.e. Multivariate Linear Regression (MLR), Multivariate Non-Linear Regression (MNLR), copula method, and Support Vector Regression (SVR) are used in this work. The fracture toughness of mode I and mode II (KIC and KIIC) is selected as the dependent variable, whereas the tensile strength, compressive strength, and elastic modulus are considered as the independent variables, respectively. The data is collected from the literature. The results obtained show that the SVR model predicts the values of KIC and KIIC with the determination coefficients (R2) of 0.73 and 0.77. The corresponding determination coefficient values of the MLR model and the MNLR model for KI and KII are R2 = 0.63, R2 = 0.72, and R2 = 0.62,0.75, respectively. The copula model predicts that the value of R2 for KI is 0.52, and for KII R2=0.69. K-fold cross-validation testing method performs for all these machine learning models. The cross-validation technique shows that SVR is the best-designed model for predicting the fracture toughness mode-I and mode-II.
S. Sepehri; R. Shirinabadi; N. Hosseini Alaee; E. Moosavi; A. H. Bangian Tabrizi
Abstract
In this research work, a 3D numerical modeling technique is proposed based on the 3D particle flow code in order to investigate the failure mechanism of rock foundations. Two series of footings with different geometries and areas are considered in this work. The failure mechanism obtained is similar ...
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In this research work, a 3D numerical modeling technique is proposed based on the 3D particle flow code in order to investigate the failure mechanism of rock foundations. Two series of footings with different geometries and areas are considered in this work. The failure mechanism obtained is similar to that of the Terzaghi’s but there is a negligible difference in between. Lastly, one equation is presented to calculate the bearing capacity based on the results achieved from the numerical model and the Mohr-Coulomb theory. The sensitivity analyses are performed on the friction angle, cohesion, and footing width. The results obtained are compared with the corresponding results given by the equations given by Terzaghi and Meyerhof. This comparison demonstrates a good agreement between them. In the friction angle sensitive analysis, the amounts of the bearing capacity diagram are very close to Meyerhof’s, which overlap with each other.
Kaustubh Sinha; Priyangi Sharma; Kanwarpreet Singh; Sushindra Kumar Gupta; Abhishek Sharma
Abstract
Land surface temperature (LST) is one of the most important geological features of any area in the present times. During the study, the information regarding the land surface temperature is calculated using the Arc-GIS software. The LANDSAT 8 (2022) and LANDSAT 4-5 (2001 and 2011) satellite images are ...
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Land surface temperature (LST) is one of the most important geological features of any area in the present times. During the study, the information regarding the land surface temperature is calculated using the Arc-GIS software. The LANDSAT 8 (2022) and LANDSAT 4-5 (2001 and 2011) satellite images are used for the calculation of LST. From the LST maps of years 2001 and 2011, a significant rise is noticed; this is due to the rapid increment in the population of the said area. A gradual increment in the LST is present between the second period of 2011-2022. A connection between the LST and the specific humidity has also been drawn in this aspect. The specific humidity in the region has seen a significant increment in the concerned time period. Overall, it is observed that the LST of the area has increased rapidly from the -12 ˚C minimum temperature in 2001 to 27 ˚C in 2022; this is because of the human activity in the area, which has ultimately catered towards the degradation of the climatic condition and environment like LST.
Exploration
Mojtaba Bazargani Golshan; Mehran Arian; Peyman Afzal; Lili Daneshvar Saein; Mohsen Aleali
Abstract
The aim is to use the Concentration-Volume (C-V) fractal model to identify high-quality parts of coal seams based on sulfur and ash concentrations. In the K1 and K7 coal seams in the North Kochakali coal deposit, 5 and 6 different populations of ash and sulfur content were obtained based on the results. ...
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The aim is to use the Concentration-Volume (C-V) fractal model to identify high-quality parts of coal seams based on sulfur and ash concentrations. In the K1 and K7 coal seams in the North Kochakali coal deposit, 5 and 6 different populations of ash and sulfur content were obtained based on the results. According to this model, sulfur and ash concentrations below 1.81% and 33.1% for the K7 seam, and below 4.46% and 37.1% for the K1 seam, respective base on Russian standard for ash and high sulfur content of North Kochakali coals were considered as appropriate values. In order to identify the high-quality parts of K1 and K7 coal seams, plans at different depths were used based on the C-V fractal model. Plans at different depths suggests that the southern part of the K1 seam and the northern part of the K7 seam have the highest-quality based on sulfur and ash concentrations, which should be considered in the extraction operation. The logratio matrix was used to compare the results of the C-V fractal model with the geological data of pyrite veins and coal ash. This matrix indicates that sulfur content above 3.8% for the K7 seam and above 4.41% for the K1 seam have good and very good correlation with pyritic veins of geological data, respectively. There are good overall accuracy (OA) values in the correlation between parts of the seam with ash concentration above 37.1% and 45.7% for the K1 and K7 seams, respectively, and the coal ash obtained from the geological data.
Rock Mechanics
M. Hosseini
Abstract
Temperature has a significant role in many actions performed on rocks. An example would be the effect of temperature on rocks in the burial of nuclear waste, geothermal energy extraction, deep oil well drilling, and fires in tunnels. In addition, due to diurnal/nocturnal as well as seasonal temperature ...
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Temperature has a significant role in many actions performed on rocks. An example would be the effect of temperature on rocks in the burial of nuclear waste, geothermal energy extraction, deep oil well drilling, and fires in tunnels. In addition, due to diurnal/nocturnal as well as seasonal temperature variations, rocks undergo a process of heating and cooling. In the present work, the effect of temperature as well as heating and cooling cycles on the rock properties was studied. The utilized samples included tuff, andesite, and sandstone. In addition to natural samples, concrete was also studied in this research work. The aim of this work was to evaluate the effect of temperature on the tensile strength of rocks and the velocity of longitudinal waves in a single heating and cooling cycle of samples as well as evaluating the effect of the number of heating and cooling cycles on the tensile strength of rocks and the velocity of longitudinal waves. In order to investigate the effect of temperature on the tensile strength of rocks as well as the velocity of longitudinal waves in a single heating and cooling cycle, the samples were heated in a furnace. After cooling the samples, the Brazilian and the sound velocity tests were carried out on them. These tests were conducted at the three temperatures of 100, 200, and 300 °C. In order to examine the effect of the number of heating and cooling cycles on the tensile strength and the velocity of longitudinal waves, the samples were heated up to the temperature of 100 °C and then cooled down in order to reach the room temperature. In this case, the work was conducted in the three modes of 5, 10, and 15 cycles. The test results showed that the velocity of longitudinal waves and the tensile strength of samples decreased but their porosity increased. Reduction in the tensile strength varied in different rocks so that the greatest and lowest reduction in the tensile strength was observed in concrete and andesite, respectively.
Exploitation
M. Mohtasham Seyfi; J. Khademi Hamidi; M. Monjezi; A. Hosseini
Abstract
Methane gas emission, accumulation, and explosion are the most important risk factors in underground coal mines. Hence, having a knowledge of methane gas emission potential in underground coal mines is of crucial importance in preventing the explosion risk, loss of life, and property, and providing miners' ...
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Methane gas emission, accumulation, and explosion are the most important risk factors in underground coal mines. Hence, having a knowledge of methane gas emission potential in underground coal mines is of crucial importance in preventing the explosion risk, loss of life, and property, and providing miners' safety. The purpose of this work is to provide the prediction maps for the C1, C2, and B2 coal seams gas contents, and to identify high gas content panels in the Parvadeh No. 1, Tabas coal mine. For this, the data collected from exploratory boreholes is put into geostatistical analysis in ArcGIS in order to estimate the coal seams gas content in unsampled points using the kriging estimation method. Reviewing the gas content maps has revealed that seams of C1, B2, and C2 have gas contents more than 15 cubic meters per ton in about 84%, 55%, and 22% of the understudied area, respectively. The present work highlights the potential and the need for implementation of a methane pre-drainage system, particularly in deeper longwall panels.
H. Azmi; P. Moarefvand; A. Maghsoudi
Abstract
Delineation of oxide and sulfide zones in mineral deposits, especially in gold deposits, is one of the most essential steps in an exploration project that has been traditionally carried out using the drilling results. Since in most mineral exploration projects there is a limited drilling dataset, application ...
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Delineation of oxide and sulfide zones in mineral deposits, especially in gold deposits, is one of the most essential steps in an exploration project that has been traditionally carried out using the drilling results. Since in most mineral exploration projects there is a limited drilling dataset, application of geophysical data can reduce the error in delineation of the sulfide and oxide zones. For this purpose, we produced a 3D model of Induced Polarization (IP) data using the ordinary kriging technique. Then the modelling results were compared with the drilling data. The results obtained showed that the 3D geophysical models would properly delineate the sulfide and oxides zones. This work presents a new application of the IP results for separation of these zones. In addition, the conducted variography in this work suggests reducing the profile spacing of dipole-dipole IP arrays down to 25 m. This would properly enrich the integration of geophysical and geological results in the modelling of gold deposits.
E. Bahri; A. Alimoradi; M. Yousefi
Abstract
There are different exploration methods, each of which may introduce a number of promising exploration targets. However, due to the financial and time constraints, only a few of them are selected as the exploration priorities. Instead of the individual use of any exploration method, it is common to integrate ...
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There are different exploration methods, each of which may introduce a number of promising exploration targets. However, due to the financial and time constraints, only a few of them are selected as the exploration priorities. Instead of the individual use of any exploration method, it is common to integrate the results of different methods in an interdependent framework in order to recognize the best targets for further exploration programs. In this work, the continuously-weighted evidence maps of proximity to intrusive contacts, faults density, and stream sediment geochemical anomalies of a set of porphyry copper deposits in the Jiroft region of the Kerman Province in Iran are first generated using the logistic functions. The weighted evidence maps are then integrated using the union score integration function in order to model the deposit type in the studied area. The weighting and integration approaches applied avoid the disadvantages of the traditional methods in terms of carrying the bias and error resulting from the weighting procedure. Evaluation of the ensuing prospectivity model generated demonstrate that the prediction rate of the model is acceptable, and the targets generated are reliable to follow up the exploration program in the studied area.
M. Hosseini Nasab; M. Noaparast; H. Abdollahi
Abstract
Due to the decreasing production of nickel and cobalt from sulfide sources, the Ni and Co extraction from the oxide ores (laterites) have become more prevalent. In this research work, the effects of calcination prior to leaching, acid concentration, percent solid, pH, and stirring speed on the nickel ...
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Due to the decreasing production of nickel and cobalt from sulfide sources, the Ni and Co extraction from the oxide ores (laterites) have become more prevalent. In this research work, the effects of calcination prior to leaching, acid concentration, percent solid, pH, and stirring speed on the nickel and cobalt recoveries from an iron-rich laterite ore sample were investigated using different organic acids. Then the response surface methodology was implemented in order to optimize the various parameters. By the design of experiments, the compound optimal concentrations of the three different organic acids (gluconic acid: lactic acid: citric acid with a ratio of 1:2:3) were 3.18 M, and S/L = 0.1, pH = 0.5, and the stirring speed = 386 rpm. With the aid of kinetic studies, a temperature of 75 °C, and a test time of 120 minutes, the highest nickel and cobalt recoveries were 25.5% and 37.6%, respectively. In the optimal conditions, the contribution of the percent solids to the nickel recovery was the most and negative, after which the contribution of pH was negative, and finally, the acid concentration had a positive effect. In the optimal conditions, the acid concentration, pH, and solid content were, respectively, important in the cobalt recovery. The SEM results showed that the surface of feed and residue particles in the optimal conditions was not significantly different, and the laboratory data was fitted to a shrinking core model. The results obtained indicated that the reaction rate was controlled by the diffusion reaction at the particle surface, and the activation energies of 11.09 kJ/mol for nickel and 28.04 kJ/mol for cobalt were consistent with this conclusion
Hafeezur Rehman; Wahid Ali; Kausar sultan Shah; Mohd Hazizan bin Mohd Hashim; Naseer Muhammad Khan; Muhammad Ali; Muhammad Kamran; Muhammad Junaid
Abstract
Support design is the main goal of the Q and rock mass rating (RMR) systems. An assessment of the Q and RMR system application in tunnelling involving high-stress ground conditions shows that the first system is more appropriate due to the stress reduction factor. Recently, these two systems have been ...
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Support design is the main goal of the Q and rock mass rating (RMR) systems. An assessment of the Q and RMR system application in tunnelling involving high-stress ground conditions shows that the first system is more appropriate due to the stress reduction factor. Recently, these two systems have been empirically modified for designing the excavation support pattern in jointed and highly stressed rock-mass conditions. This research work aims to highlight the significance of the numerical modelling, and numerically evaluate the empirically suggested support design for tunnelling in such an environment. A typical horse-shoe-shaped headrace tunnel at the Bunji hydropower project site is selected for this work. The borehole coring data reveal that amphibolite and Iskere Gneiss are the main rock mass units along the tunnel route. An evaluation of the proposed support based on the modified empirical systems indicate that the modified systems suggest heavy support compared to the original empirical systems. The intact and mass rock properties of the rock units are used as the input for numerical modelling. From numerical modelling, the axial stresses on rock bolts, thrust bending moment of shotcrete, and rock load from modified RMR and Q-systems are compared with the previous studies. The results obtained indicate that the support system designed based on modified version of the empirical systems produce better results in terms of tunnel stability in high-stress fractured rock mass conditions.
Debasmita Basu; Smriti Mishra
Abstract
Although mine closure problems have been researched in the past, little to no research has been dedicated to the post-reclamation impacts of abandoned mine closure. Even though reclamation has been an age-old identified technique, stakeholders’ perception has played an important role in defining ...
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Although mine closure problems have been researched in the past, little to no research has been dedicated to the post-reclamation impacts of abandoned mine closure. Even though reclamation has been an age-old identified technique, stakeholders’ perception has played an important role in defining the implementation procedure. Therefore, this study intends to identify the various implementation procedures through a rigorous literature assessment of 112 publications, identified from various sources. Theoretical and practical complications have been identified in the fields of environmental, socio-cultural and economic impacts of mine closure. The study unveiled that the most implemented reclamation strategy was intensive and non-intensive recreation/tourism-based reclamation techniques. Thus the study paves the way for the incorporation of an interdisciplinary strategy through cooperation between various stakeholders and research fields for the long-term viability of a mining site restoration.
Mineral Processing
S. Feizollahi; A. Azizi
Abstract
The extraction behavior of Cu(II) ions from a real sulfate liquor obtained from the heap leaching stage of a copper oxide ore was investigated using a chelating reagent, Chemorex CP-150 in kerosene. A comparative study was also carried out on the extraction capability of Cu(II) ions using other solvents ...
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The extraction behavior of Cu(II) ions from a real sulfate liquor obtained from the heap leaching stage of a copper oxide ore was investigated using a chelating reagent, Chemorex CP-150 in kerosene. A comparative study was also carried out on the extraction capability of Cu(II) ions using other solvents including D2EHPA and Cyanex 272.Chemorex CP-150 demonstrated an effective and selective extraction performance of copper with the amount of extracted Fe less than 15%. Also the results obtained indicated that more than 66.4% and 96.99% of Cu were transferred to the organic phase in a single extraction stage using 15% (v/v) Chemorex CP-150 at the A:O phase ratios of 1:1 and 1:4, respectively. In addition, the McCabe-Thiele diagram exhibited that two extraction stages were required to achieve the maximum amount of Cu at a 1:1 phase ratio under the optimal conditions (25 °C, pH 2.5, and 20 min contact time). Also, thermodynamic data proved that the extraction process was slightly endothermic (ΔH = 7.62 kJ/mol), indicating the relatively smaller heat effects on the formation of a single complex species (CuR2). Stripping of copper from the loaded organic phase was also conducted, and it was found that ~99.38% copper could be recovered using 165 g/L H2SO4 at a 2:1 A:O phase ratio after 5 minutes stripping.
Rock Mechanics
K. Abdolghanizadeh; M. Hosseini; M. Saghafiyazdi
Abstract
Natural and artificial materials including rocks and cement-based materials such as concrete and cement mortar are affected both physically and chemically by various natural factors known as weathering factors. The freeze-thaw process, as a weathering factor, considerably affects the properties of rocks ...
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Natural and artificial materials including rocks and cement-based materials such as concrete and cement mortar are affected both physically and chemically by various natural factors known as weathering factors. The freeze-thaw process, as a weathering factor, considerably affects the properties of rocks and concrete. Therefore, the effect of the freeze-thaw process on the physical and mechanical properties of materials should be taken into account in areas with the risk of this process. Given that few studies have been conducted on the effect of the freeze-thaw process on the fracture toughness, in this work, we aimed at investigating the effects of the freeze-thaw cycles and freezing temperature on the mode I and mode II fracture toughness of cement mortar. To this end, specimens were exposed to 0, 5, 10, 20, and 30 freeze-thaw cycles, and the mode I and mode II fracture toughness was determined in different cycles. The effect of freezing temperature in a freeze-thaw cycle on the mode I and mode II fracture toughness was also investigated. The damage factor was also defined based on the effective porosity of cement mortar, and its changes with the number of freeze-thaw cycles and mode I and mode II fracture toughness were studied. Finally, the decay function model provided by Mutluturk was investigated. According to the results obtained, the mode I and mode II fracture toughness of cement mortar decreased linearly with increase in the number of freeze-thaw cycles. The mode I and mode II fracture toughness decreased linearly with increase in the freezing temperature in a freeze-thaw cycle. The damage factor increased with increase in the number of freeze-thaw cycles, and, additionally, its relationship with mode I and mode II fracture toughness exhibited a linear behavior.
Rock Mechanics
Ekin Koken
Abstract
In this study, several soft computing analyses are performed to build some predictive models to estimate the uniaxial compressive strength (UCS) of the pyroclastic rocks from central Anatolia, Turkey. For this purpose, a series of laboratory studies are conducted to reveal physico-mechanical rock properties ...
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In this study, several soft computing analyses are performed to build some predictive models to estimate the uniaxial compressive strength (UCS) of the pyroclastic rocks from central Anatolia, Turkey. For this purpose, a series of laboratory studies are conducted to reveal physico-mechanical rock properties such as dry density (ρd), effective porosity (ne), pulse wave velocity (Vp), and UCS. In soft computing analyses, ρd, ne, and Vp are adopted as the input parameters since they are practical and cost-effective non-destructive rock properties. As a result of the soft computing analyses based on the classification and regression trees (CART), multiple adaptive regression spline (MARS), adaptive neuro-fuzzy inference system (ANFIS), artificial neural networks (ANN), and gene expression programming (GEP), five robust predictive models are proposed in this study. The performance of the proposed predictive models is evaluated by some statistical indicators, and it is found that the correlation of determination (R2) value for the models varies between 0.82 – 0.88. Based on these statistical indicators, the proposed predictive models can be reliably used to estimate the UCS of the pyroclastic rocks.
H. Hassani; A. Agah
Abstract
In this work, Fe3O4@TiO2@V2O5 is synthesized via functionalization of Fe3O4 with TiO2 and then modifying with V2O5. The characterization of the synthesized nano-catalyst is performed using several methods including XRD, TEM, SEM, EDS, TGA, and VSM. This nano-catalyst impressively catalyzes the synthesis ...
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In this work, Fe3O4@TiO2@V2O5 is synthesized via functionalization of Fe3O4 with TiO2 and then modifying with V2O5. The characterization of the synthesized nano-catalyst is performed using several methods including XRD, TEM, SEM, EDS, TGA, and VSM. This nano-catalyst impressively catalyzes the synthesis of 3,3-di-indolyl oxindoles (with an 85-98% yield in 10-80 minutes). Furthermore, the introduced catalyst can be reused in at least five successive reactions with no significant catalytic activity loss. The effects of some influencing parameters on the catalytic efficacy of Fe3O4@TiO2@V2O5 are also assessed. The appropriate product is attained for a wide range of isatins and indoles. Using an inexpensive and reusable catalyst and using the H2O solvent puts this methodology in the green chemistry domain.
H. Geranian; Z. Khajeh Miry
Abstract
In this work, we aim to identify the mineralization areas for the next exploration phases. Thus, the probabilistic clustering algorithms due to the use of appropriate measures, the possibility of working with datasets with missing values, and the lack of trapping in local optimal are used to determine ...
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In this work, we aim to identify the mineralization areas for the next exploration phases. Thus, the probabilistic clustering algorithms due to the use of appropriate measures, the possibility of working with datasets with missing values, and the lack of trapping in local optimal are used to determine the multi-element geochemical anomalies. Four probabilistic clustering algorithms, namely PHC, PCMC, PEMC, PDBSCAN, and 4138 stream sediment samplings, are used to divide the samples into the three clusters of background, possible anomaly, and probable anomaly populations. In order to determine these anomalies, ten and eight metal elements are selected as the chalcophile and siderophile elements, respectively. The results obtained show the areas of approximately 500 and 5,000 km2 as the areas of the probable and possible anomalies, respectively. The composite geochemical anomalies of the chalcophile and siderophile elements are mostly dominant in the metamorphic-acidic-intermediate rock units and the alkaline-metamorphic-intermediate rock units of the studied area, respectively. Besides, the obtained anomalies of the four clustering algorithms also cover about 65% of the mineralized areas, all mines, and almost 60% of the alteration areas. The validity criterion of the clustering methods show more than 70% validity for the obtained anomalies. The results obtained indicate that the probabilistic clustering algorithms can be an appropriate statistical tool in the regional-scale geochemical explorations.
Saeed Nazari; Alireza Arab Amiri; Abolghasem Kamkar Rouhani; Fereydoun Sharifi
Abstract
In this work, we simulate the frequency-domain helicopter-borne electromagnetic (HEM) data over the two-dimensional (2D) and three-dimensional (3D) earth models. In order to achieve this aim, the vector Helmholtz equation is used to avoid the convergence problems in Maxwell’s equations, and the ...
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In this work, we simulate the frequency-domain helicopter-borne electromagnetic (HEM) data over the two-dimensional (2D) and three-dimensional (3D) earth models. In order to achieve this aim, the vector Helmholtz equation is used to avoid the convergence problems in Maxwell’s equations, and the corresponding fields are divided into primary and secondary components. We use the finite difference method on a staggered grid to discretize the equations, which can be performed in two ways including the conventional and improved finite difference methods. The former is very complex in terms of programming, which causes errors. Furthermore, it requires different programming loops over each point of the grid, which increases the program’s running time. The latter is the improved finite difference method (IFDM), in which pre-made derivative matrices can be used. These pre-made derivative matrices can be incorporated into the derivative equations and convert them directly from the derivative form to the matrix form. After having the matrix form system of linear equations, Ax = b is solved by the quasi-minimal residual (QMR). IFDM does not have the complexities of the conventional method, and requires much less execution time to form a stiffness or coefficient matrix. Moreover, its programing process is simple. Our code uses parallel computing, which gives us the ability to calculate the fields for all transmitter positions at the same time, and because we use sparse matrices thorough the code memory space, requires to store the files is less than 100 MB compared with normal matrices that require more than 15 GB space in the same grid size. We implement IFDM to simulate the earth’s responses. In order to validate, we compare our results with various models including the 3D and 2D models, and anisotropic conductivity. The results show a good fit in comparison with the FDM solution of Newman and the appropriate fit integral equations solution of Avdeev that is because of the different solution methods.
