Mineral Processing
Jiaye Li; Jing Zhao; Zebin Wang; Huan Liu; Qing Wen; Jinling Yin; Ze Li; Yang Lei; Guiling Wang
Abstract
Traditional graphite has safety and environmental issues, associated with fluorine purification. To address these issues, an energy-saving and efficient graphite purification process can be explored through the acid leaching method with composite additives. The acid leaching process was studied and optimized ...
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Traditional graphite has safety and environmental issues, associated with fluorine purification. To address these issues, an energy-saving and efficient graphite purification process can be explored through the acid leaching method with composite additives. The acid leaching process was studied and optimized in detail using the controlled variable method including the effects of the soaking time and temperature on the graphite purification process. Then the response surface method was used to simulate the orthogonal experiment of graphite purification to verify the correctness of the single-factor, experiment. The purity and micromorphology of the graphite samples at each stage were characterized and tested. The experimental results showed that the optimal liquid-to-solid ratio of the acid solution and graphite was 20:1, which could make the fixed carbon content reach 99.77%. On the basis of these optimal process conditions, the addition types were further explored. The experimental result showed that the best addition was ascorbic acid and EDTA, which could reduce the content of various impurities in the graphite raw material without destroying the microstructure of the graphite. Benefitting from the addition of compound additives in the two-step process, almost all the metal ions were leached from the graphite. After the acid and water leaching, the fixed carbon content of graphite could reach 99.96%. The process parameters proposed in this paper were scientifically verified by both the single-factor and multi-factor experiments, and innovative and effective additives were introduced in different steps to make the graphite purity break through 99.9%, which was difficult to reach by the traditional method.
Mineral Processing
Ahmed Mohammedelmubarak Ah Abbaker; Nevzat Aslan
Abstract
This work optimizes coarse particle flotation using microbubble-assisted flotation in a cationic environment created by dodecylamine (DDA). The flotation efficiency of coarse quartz particles (D50 = 495 μm) was investigated through an examination of the interactions between microbubbles (20-30 μm), ...
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This work optimizes coarse particle flotation using microbubble-assisted flotation in a cationic environment created by dodecylamine (DDA). The flotation efficiency of coarse quartz particles (D50 = 495 μm) was investigated through an examination of the interactions between microbubbles (20-30 μm), the cationic environment, and various operational parameters. A systematic approach utilizing factorial and Box-Behnken experimental designs was employed to evaluate the effects of the multiple variables. These variables included the dodecylamine (DDA) concentration, methyl isobutyl carbinol (MIBC) concentration, impeller speed, pulp density, the addition of fine particles, and the presence of microbubbles. The DDA concentration and the impeller speed significantly impacted the coarse particle recovery, while microbubbles increased recovery by 15% under non-optimized conditions; optimization revealed a more negligible difference. The optimized conditions achieved maximum recoveries of 99.47% and 97.88% with and without microbubbles, respectively, indicating the minimal effect when other parameters were optimized. This research work shows that a careful optimization of the flotation parameters can achieve high coarse particle recovery rates, with microbubbles playing a less significant role than anticipated. These findings suggest that optimizing the conventional parameters may be more crucial than the microbubble introduction for enhancing the flotation efficiency of larger particles. The work contributes to our understanding of coarse particle flotation, and provides insights for improving the mineral processing techniques for challenging the particle sizes.
Mineral Processing
Ashraf Alsafasfeh; Anum Razzaq; Abeer Sajid; Maryam Nazir; Muhammad Badar Hayat; Mirza Zaid
Abstract
Palygorskite (PAL), also known as attapulgite, is a clay mineral prized for its nanorod-like silicate structure and fibrous morphology. The traditional PAL purification methods often involve wet gravity separation techniques such as sedimentation and screening, which require significant water usage and ...
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Palygorskite (PAL), also known as attapulgite, is a clay mineral prized for its nanorod-like silicate structure and fibrous morphology. The traditional PAL purification methods often involve wet gravity separation techniques such as sedimentation and screening, which require significant water usage and pose sustainability challenges, especially in the water-scarce regions. This work introduces a novel, environmentally sustainable dry beneficiation method for PAL. A large PAL sample with 41.7% content and 10% moisture was crushed, ground using a pin mill, and classified into three particle size fractions:
-0.088 mm + 0.066 mm, -0.066mm +0.044 mm, and -0.044 mm. These fractions were treated with an air classifier. A Box-Behnken experimental design was employed to investigate the effects of particle size, shutter opening, and motor speed on the classification efficiency. The optimal parameters for grade were 400 rpm motor speed, shutter opening of 1 mm, and feed size of -0.066 mm + 0.044 mm. For the recovery, the optimal conditions were 1200 rpm motor speed, shutter opening of 2.5 mm, and feed size of -0.044 mm. The most favorable balance of grade (67.8%) and recovery (53.2%) was achieved with a motor speed of 1200 rpm, shutter opening of 4 mm, and feed size of -0.066 mm + 0.044 mm. The work concludes that air classification significantly enhances the PAL beneficiation process, with a 50% increase in grade, and recommends exploring the low shear grinding techniques for further improvement.
Mineral Processing
Rim Amata; Mohamed Bounouala; Ashraf Alsafasfeh; Amar Amata; Sofiane Bouabdallah
Abstract
The Djebel Onk region of Algeria faces a significant environmental concern, related to phosphate mining waste. Although these mining tailings contain relatively low quantities of valuable minerals, they still include up to 25% P₂O₅ in the particle size range of 0.25-1 mm (-1-+0.25), suggesting the ...
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The Djebel Onk region of Algeria faces a significant environmental concern, related to phosphate mining waste. Although these mining tailings contain relatively low quantities of valuable minerals, they still include up to 25% P₂O₅ in the particle size range of 0.25-1 mm (-1-+0.25), suggesting the potential for recovery and reuse. This research, based on the Bir El Ater area, explores the methods to recover phosphate-rich minerals, optimizing their reuse. Two techniques were explored: calcination, a heat treatment altering mineral chemistry, and electrostatic separation, which uses the electrical properties to separate minerals. The black phosphate tailings collected from the curved grids of wet processing were subjected to detailed analysis using Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), and X-Ray Fluorescence (XRF), to examine their mineralogical and chemical properties. The results showed a notable improvement in the P₂O₅ concentration, with electrostatic separation reaching a 30.03% content and an 89% recovery rate, while calcination achieved the 30.91% content with a 91% recovery rate. These results highlight the effectiveness of both methods in recovering phosphate from mining tailings, contributing to a better waste management, a more efficient resource use, and a reduced environmental footprint. They also suggest sustainable recovery pathways, especially for the regions facing water scarcity, where flotation is impractical. With the ability to achieve high recovery rates without chemical inputs, calcination and electrostatic separation stand out as environmentally sustainable options for global phosphate beneficiation.
Mineral Processing
reza zolfaghari; Mohammad Karamoozian
Abstract
In flotation, entrainment (ENT) affects the recovery of the concentrate, and the entrainment model is often supposed to be only a function of particle size in models. Some research shows that other variables may also significantly affect ENT. In this study, some flotation experiments executed using a ...
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In flotation, entrainment (ENT) affects the recovery of the concentrate, and the entrainment model is often supposed to be only a function of particle size in models. Some research shows that other variables may also significantly affect ENT. In this study, some flotation experiments executed using a mixture of pure quartz as the valuable mineral and a pure magnetite sample as the gangue mineral to investigate the effects of other variables, such as solid content, airflow rate, frother, and collector dosages, on ENT. The results showed ENT varied from 0.071 to 0.851 is different, while the entrainment recovery was between 0.006 to 0.23, which means that the difference is statistically significant. ENT affected by (1) collector dosage, (2) frother dosage, (3) solid content, (4) the interaction between airflow rate and solid content and, (5) the interaction between airflow rate and frother dosage. An empirical statistical model is presented based on operational parameters. As the present models for ENT incorporate just particle size, it is not enough to predict gangue recovery in industrial applications by keeping the operating conditions constant. This novel model can predict ENT based on different operational parameters. The developed model is presented based on the particle mass by changing the operation parameters.
Mineral Processing
Seyyed Mohsen Zamzami; Javad Vazifeh Mehrabani
Abstract
In this research, solid phase settling process from the liquid phase were optimized simultaneously on the different responses, using the response surface methodology (RSM). The effect of solid percentage, flocculant dosage, temperature, and pulp pH were evaluated on the responses of solid settling velocity, ...
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In this research, solid phase settling process from the liquid phase were optimized simultaneously on the different responses, using the response surface methodology (RSM). The effect of solid percentage, flocculant dosage, temperature, and pulp pH were evaluated on the responses of solid settling velocity, water turbidity, viscosity and density of settled pulp. The results showed that by increasing the flocculant dosage from 0.5 to 3.5 g/ton, settled pulp viscosity decreases from 49.05 cSt to 17.54 cSt. The higher values of pulp pH as well as low amount of solid percentage resulted in high water turbidity, which shows the lack of contact between flocs and suspended particles. The results indicated that the pulp solid percentage and the flocculants dosage are the most significant parameters on the responses. Optimum test conditions were obtained in industrial mode by using 5 g/t flocculant, solid percentage 23.96%, pH=7.5 temperature of the pulp 21.5°C in which condition, settling rate, pulp viscosity, pulp density and water turbidity were predicted to be 13.23 cm/min, 5.1 cSt, 1.61 g/cm3 and 15.7 NTU respectively. Repetition test in the model predicted optimum condition was carried out and verified the predicted optimized condition.
Mineral Processing
Mohammad Jahani Chegeni; Sajad Kolahi; Asghar Azizi
Abstract
Consumed energy is the most important issue and concern in industrial ball mills, and includes a major part of the costs of mineral processing plants. By using suitable liners and the optimal lifter count, the energy of the mill is properly transferred to the balls. In Part 1 of this research work, five ...
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Consumed energy is the most important issue and concern in industrial ball mills, and includes a major part of the costs of mineral processing plants. By using suitable liners and the optimal lifter count, the energy of the mill is properly transferred to the balls. In Part 1 of this research work, five types of liners, i.e. Lorain, Osborn, Rib, cuboid, and Hi-lo, are examined. These liners all have separate lifters with the same volume. Their difference is in the width, height, and type of lifter profile. First, all types of liners are simulated with four lifters using the Discrete Element Method (DEM). Then the lifter count is increased four by four to fill the entire wall of the mill with lifters. Based on this, Lorain liner from 4 to 24 lifters, Osborn liner from 4 to 120 lifters, Rib liner from 4 to 40 lifters, and cuboid and Hi-lo liners from 4 to 64 lifters are simulated. For the first time, the kinetic (KE) and potential (PE) energies as well as the sum of these two energies (TE) of all the balls are calculated, and compared in the entire duration of the simulation from 0–13s for all the liner types and lifter counts mentioned above. Finally, by using data related to KE, PE, and TE for each type of liner, the optimal lifter count is obtained. Accordingly, 16 to 20 lifters are recommended for the Lorain liner, 64 to 76 lifters for the Osborn liner, 24 to 32 lifters for the Rib liner, 44 lifters for the cuboid liner, and 36 to 44 lifters for the Hi-lo liner.
Mineral Processing
Sajad Kolahi; Mohammad Jahani Chegeni; Asghar Azizi
Abstract
In Part 2 of this research work, five types of liners, i.e. wave, step, step@, ship-lap, and ship-lap@, are examined. These liners all have similar connected lifters with different volumes. Their difference is in the width, height, and type of the lifter profile. All the five liner types, from 8 to 64 ...
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In Part 2 of this research work, five types of liners, i.e. wave, step, step@, ship-lap, and ship-lap@, are examined. These liners all have similar connected lifters with different volumes. Their difference is in the width, height, and type of the lifter profile. All the five liner types, from 8 to 64 lifters, are simulated using the Discrete Element Method (DEM). In this research work, for the first time, data from the sum of the kinetic and potential energies of individual balls (79,553 particles) are used to find the appropriate range for the number of lifters. In other words, the kinetic and potential energies of all particles within the system (inside the ball mill) are the basis for determining the appropriate number of lifters. The results suggest that for the wave liner, the appropriate range of the number of lifters is between 8 and 16, for the step, step@, and ship-lap liners; it is between 12 and 20, and for the ship-lap@ liner, it is between 8 and 20. In fact, using the data on the kinetic and potential energies of the balls inside the mill, it is possible to determine the appropriate range of the number of lifters, which is done for the first time in this study. In general, it is suggested that the data on the kinetic and potential energies of the balls can be used to determine the number of mill lifters, and unlike what has been done. So far, by other researchers, the number of mill lifters should not be determined solely by using its diameter or the dimensions of the lifters. Also the effect of mill-rotation direction on the values of kinetic and potential energies in step and ship-lap liners is investigated. It is shown that the step@ and ship-lap@ liners transfer more energy to the balls than the step and ship-lap liners, and have a suitable direction of rotation.
Mineral Processing
Sahil Kumar; Ravi Kumar Sharma
Abstract
Landslides affecting life and property losses has become a serious threat in various countries worldwide which highlights the importance of slope stability and mitigation. The methods and tools employed for slope stability analysis, ranging from traditional limit equilibrium methods to worldly-wise numerical ...
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Landslides affecting life and property losses has become a serious threat in various countries worldwide which highlights the importance of slope stability and mitigation. The methods and tools employed for slope stability analysis, ranging from traditional limit equilibrium methods to worldly-wise numerical modelling techniques. It focuses on the importance of accurate and reliable data collection, including geotechnical investigations, in developing precise slope stability assessments. Further, it also addresses challenges associated with predicting and mitigating slope failures, particularly in dynamic and complex environments. Mitigation strategies for unstable slopes were systematically reviewed of different researchers, encompassing both traditional and innovative measures. Traditional methods, such as retaining walls and drainage systems, the mitigation strategies were explored, emphasizing both preventive measures and remedial interventions. These include the implementation of engineering solutions such as slope structures, and Matrix Laboratory (MATLAB) techniques along with the comprehensive analysis of four prominent slope stability assessment tools: Rock Mass Rating (RMR), Slope Mass Rating (SMR), and the Limit Equilibrium Method (LEM). The comparative analysis of these tools highlights their respective strengths, limitations, and areas of application, providing researchers, authors, and practitioners with valuable insights to make informed choices based on project-specific requirements. To ensure the safety and sustainability of civil infrastructure, a thorough understanding of geological, geotechnical, and environmental factors in combination with cutting-edge technologies is required. Furthermore, it highlights the important role that slope stability assessment and mitigation play a major role in civil engineering for infrastructure development and mitigation strategies.
Mineral Processing
Alireza Javadi
Abstract
The main and economic mineral of antimony is stibnite or antimony sulfide, and the research and processes in the world are based on it, and oxide minerals are not considered among the economic and important reserves of antimony due to the difficulty of processing and the lack of optimal efficiency of ...
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The main and economic mineral of antimony is stibnite or antimony sulfide, and the research and processes in the world are based on it, and oxide minerals are not considered among the economic and important reserves of antimony due to the difficulty of processing and the lack of optimal efficiency of the flotation method. On the other hand, taking into account that a large part of the antimony reserve of Sefidabeh is made up of low-grade oxidized ore; this research on the method of economic extraction and the possibility of recovering this type of reserve will be important due to the strategic nature of antimony metal. According to the experiments conducted in this research, the effective parameters for flotation include: pH, collector concentration, activator concentration, depressant concentration, activator type, and humic acid concentration. DX7 software was used for statistical modeling of experiments. Based on the above parameters, the design of the experiment was carried out using a partial factorial method and finally the number of 16 experiments was determined for the effect of the above factors on the grade and weight recovery of the sample. Antimony ore flotation with a grade of 4.32% was carried out in a two-stage method. In this method, in the first stage, flotation of antimony sulfur (stibnite, Sb2S3) was performed at a specific pH by adding the activator of copper sulfate or lead nitrate and the depressant together, potassium amyl xanthate collector and MIBC. In the second stage of flotation, the tailings of the first stage of flotation for antimony oxides were treated with a sodium oleate collector (with determined concentrations) at a specific pH by adding copper sulfate or lead nitrate activator, sodium oleate collector and humic acid and MIBC frother agent. The interaction between pH and activator concentration (BD) has a direct effect on the amount of concentrated antimony, with an increase in pH from 6 to 8 antimony when using an activator concentration of 300 g/t, and a decrease when using an activator concentration of 500 g/t. Flotation was done. In the best conditions, with two-stage flotation of antimony, 68.99% recovery and 13.32 grade were obtained.
Mineral Processing
Ahmad Abbasi Gharaei; Bahram Rezai; Hadi Hamidian Shormasti
Abstract
This paper examines the performance of Atmospheric Leaching (AL) and High-Pressure Acid Leaching (HPAL) on nickel laterite, classified as limonite. The study, conducted on a laboratory scale, involved temperatures of 35-95°C for AL and 220-250°C for HPAL. Nickel and cobalt contents were found ...
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This paper examines the performance of Atmospheric Leaching (AL) and High-Pressure Acid Leaching (HPAL) on nickel laterite, classified as limonite. The study, conducted on a laboratory scale, involved temperatures of 35-95°C for AL and 220-250°C for HPAL. Nickel and cobalt contents were found to be 0.7% and 0.04%, respectively. AL achieved an 89% yield of Al with a pH of 0.2 and a 14-hour leaching time, while nickel and iron recoveries reached 92% and 87% after 20 hours, with an acid consumption of 1.2 kg H2SO4 per 100 kg laterite (dry) at pH 0.2. Leaching experiments at 220-250°C for 2 hours showed similar nickel recovery rates, indicating no improvement beyond 240°C. Hematite, a stable compound associated with nickel, hindered its release during HPAL due to its resistance to leaching. Nickel yields remained around 90% in both AL and HPAL tests. Iron behavior differed significantly between the two methods, with HPAL dissolving iron initially but transforming it into hematite in situ, leading to lower net acid consumption compared to AL. The leaching mechanism for iron oxides followed empirical power law kinetics of order 1.5 with activation energies of 36.23 and 25.09 kJ/mol for Ni and Fe, respectively.
Mineral Processing
Reza Khodadadi Bordboland; Asghar Azizi; Mohammad Reza Khani
Abstract
The global growth of aluminum demand with the modernization of our society has led to the interest in developing alternative methods to produce aluminum from non-bauxite and low-grade resources such as shale bauxites. For such reserves, the conventional Bayer process is challenging and is not efficient ...
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The global growth of aluminum demand with the modernization of our society has led to the interest in developing alternative methods to produce aluminum from non-bauxite and low-grade resources such as shale bauxites. For such reserves, the conventional Bayer process is challenging and is not efficient to extract aluminum, and the sintering process is known to be effective. Thus, this study aimed to scrutinize the technical feasibility of alumina extraction from an Iranian low-grade (shale) bauxite ore containing 36.22% Al2O3, 22.11% SiO2, 20.42% Fe2O3, 3.33% TiO2, and 3.13% CaO. In this regard, the sintering process with lime-soda followed by alkaline leaching was adopted to extract alumina, and response surface modeling was employed to assess the important parameters such as the sintering temperature, Na2O(caustic) concentration, CaO/SiO2 molar ratio, and Na2O/Al2O3 molar ratio. The findings indicated that the extraction rate improved by increasing the sintering temperature and CaO/SiO2 ratio and decreasing the Na2O(caustic) dose and Na2O/Al2O3 ratio. It was also found that the Na2O(caustic) concentration, sintering temperature, and interactive effect of Na2O(caustic) concentration with Na2O/Al2O3 ratio had the greatest influence on the extraction efficiency. The process optimization was conducted applying the desirability function approach, and more than 71% of Al2O3 was extracted at 1150 °C sintering temperature, 2.1 CaO/SiO2 molar ratio, 0.9 Na2O/Al2O3 molar ratio and 30 g/L Na2O(caustic) dose. Ultimately, it was concluded that a lime-soda sintering process at 1150 °C followed by one-step alkaline leaching with Na2O(caustic) at 90 °C could be metallurgically efficient for treating the low-grade (shale) bauxites.
Mineral Processing
Rahul Shakya; Manendra Singh
Abstract
Due to the critical nature of seismic risk in metro tunnels, the seismic response of underground tunnels is a highly delicate topic. The seismic response of a sub-surface structure depends more on the properties of the surrounding ground and the induced earth deformation during an earthquake than on ...
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Due to the critical nature of seismic risk in metro tunnels, the seismic response of underground tunnels is a highly delicate topic. The seismic response of a sub-surface structure depends more on the properties of the surrounding ground and the induced earth deformation during an earthquake than on the structure's inertial properties. This paper examines the seismic response of a typical section of the underground tunnel of Delhi Metro Rail Corporation (DMRC) between Rajiv Square and Patel Square in New Delhi's Connaught Place. Three-dimensional elasto-plastic analysis of Delhi metro underground tunnels under the seismic loading has been performed by finite element method using the Plaxis 3D software. Additionally, the influence of various boundary conditions on the dynamic response of metro tunnels has been examined. A comparison of the three-dimensional analysis with the two-dimensional plane-strain analysis has also been made. Horizontal displacements were experienced maximum compared to the longitudinal and vertical displacements in the soil-tunnel system. In dynamic analysis, the absorbent boundary is much more effective in controlling the displacements and the induced acceleration than the elementary boundary or the free-field boundary.
Mineral Processing
Mohammadreza Shahbazi; Hadi Abdollahi; Sied Ziaeddin Shafaei; Ziaeddin Pourkarimi; Sajjad Jannesar Malakooti; Ehsan Ebrahimi
Abstract
Tabas coal possesses favorable plastometric properties that make it suitable for use in metallurgical industries as coking coal. However, its high sulfur content, which stands at approximately 2%, poses a significant environmental pollution risk. Additionally, reducing ash content to below 10% is a critical ...
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Tabas coal possesses favorable plastometric properties that make it suitable for use in metallurgical industries as coking coal. However, its high sulfur content, which stands at approximately 2%, poses a significant environmental pollution risk. Additionally, reducing ash content to below 10% is a critical objective of this study to prevent a decline in coal's thermal efficiency in the metallurgical industries. This research work investigates the removal of sulfur and ash from Tabas coal samples using the biological methods including bioflotation and bioleaching. Initially, a combination of mesophilic bacteria including Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans, and Leptosprillium ferrooxidans were employed in the bioflotation method to detain pyrite sulfur in the Tabas coal samples. The highest reduction percentages of pyrite sulfur and ash were equal to 62% and 54.18%, respectively. In the next stage, bioleaching experiments were conducted, the effect of the test time, percentage of bacteria by volume, percentage of coal solids, and absence of bacteria on the amount of sulfur and ash removal was investigated. The test time emerged as the most critical factor. The best sulfur removal was achieved using bioleaching, with a maximum removal of 72.43%, observed for the PE coal sample. Bioflotation also achieved significant sulfur removal, with a maximum removal of 61% observed for the same sample. On the other hand, the best ash removal was achieved using bioflotation, with a maximum removal of 68.98% observed for the PE coal sample, and a maximum removal of 69.34% observed for the B4B2 coal sample using bioleaching. Finally, this research work conducted a comparison of biological methods to determine the amount of sulfur and ash reduction achieved. The results showed that both bioleaching and bioflotation were effective for coal desulfurization and ash removal, with bioleaching performing slightly better for sulfur removal and bioflotation performing slightly better for ash removal.
Mineral Processing
Ali Nikouei Mahani; Mohammad Karamoozian; Mohammad Jahani Chegeni; Mohammad Mahmoodi Meymand
Abstract
Generally, mineral processing plants generate a large quantity of waste in the form of fine particles. The flotation speed of mineral microbubbles by coarse bubbles is dramatically higher than that of individual particles. The advantage of microbubbles is due to the increase of binding efficiency of ...
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Generally, mineral processing plants generate a large quantity of waste in the form of fine particles. The flotation speed of mineral microbubbles by coarse bubbles is dramatically higher than that of individual particles. The advantage of microbubbles is due to the increase of binding efficiency of conventional bubbles with fine particles coated with microbubbles. Here, the focus is on reducing chemicals consumption and improving recovery. After preparing a representative sample, XRF, XRD, and mineralogical analyses were performed. Then 50 experiments were selected by experimental design using the response surface method (RSM), and in the form of central Composite design (CCD) by (design expert) DX 13 software. The interactions of collector consumption, frother agent, pH, particle size, and solid percentage were investigated, and 25 experiments using typical flotation and without nano-microbubbles and others with nano-microbubbles were conducted. The laboratory standard limit of the collector used in the pilot plant of the Sarcheshmeh Copper copper complex is 40 g/t (25 g/t of C7240 plus 15 g/t of Z11). Here, by consuming 20 g/t of collector in the absence of nanomicrobubbles, a recovery of 79.96% and in the presence of nanomicrobubbles, a recovery of 80.07% was obtained, that is a 50% reduction in collector consumption and a 0.11% increase in recovery was observed. Also the laboratory standard limit of frother used in the pilot plant of Sarcheshemeh Copper Complex is 30 g/t (15 g/t of MIBC plus 15 g/t of A65). Here, by using 10 g/t of frother in the absence of nanomicrobubbles, a recovery of 78.12%, and in the presence of nanomicrobubbles, a recovery of 82.05% was obtained. In other words, a decrease of 66.6% in the consumption of frother and an increase of 1.93% in recovery was observed.
Mineral Processing
Zehra Khan; Abhishek Sharma
Abstract
Due to rapid growth in infrastructure sector, the construction of high-rise buildings is becoming very popular among all the countries. Engineers face significant issues with high rise buildings, particularly in terms of structural and foundation aspects. Many old design approaches can't be used with ...
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Due to rapid growth in infrastructure sector, the construction of high-rise buildings is becoming very popular among all the countries. Engineers face significant issues with high rise buildings, particularly in terms of structural and foundation aspects. Many old design approaches can't be used with certainty since they involve extrapolation far beyond the domains of existing experience, hence structural and geotechnical engineers are being compelled to use more advanced analysis and design methodologies. The current study is an attempt to predict the bearing capacity and settlement behavior of piled-raft footing when embedded into cohesionless deposit. The numerical analysis has been carried out to examine the effect of numerous key parameters of pile and raft such as pile length (10, 15, 20 m), pile diameter (0.3, 0.4, 0.5 m), pile number (16, 20, 24), pile spacing (2D, 3D, 4D) (where “D” is diameter of the pile), raft thickness (0.4, 0.5, 0.6 m), and angle of internal friction of soil (25°, 30°, 35°) on load-settlement behavior of the piled- raft foundation using ABAQUS software. A constant spacing between the piles, i.e. 3D was used throughout the analysis. The results of numerical investigation revealed an improvement in bearing capacity and a reduction in settlement value on increasing length, diameter and number of piles and also with increasing angle of internal friction. The current study not only increases the bearing capacity of the foundation but provides a cost-effective foundation technique to engineers.
Mineral Processing
Satya Sai Srikant; Raghupatruni Bhima Rao
Abstract
The present paper deals with the development of process flowsheet for recovery of high-grade graphite from rougher graphite concentrate for use in industrial applications. In the present investigation, since the coarser graphite flakes have a higher demand, an attempt is made at every stage of comminution, ...
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The present paper deals with the development of process flowsheet for recovery of high-grade graphite from rougher graphite concentrate for use in industrial applications. In the present investigation, since the coarser graphite flakes have a higher demand, an attempt is made at every stage of comminution, and flash flotation experiments have been carried out, and the end product obtained by stage comminution followed by flotation has been further subjected to alkali pressure leaching followed by grinding and flotation to recover industrial grade graphite concentrate. During this stage grinding, an additive, a depressant that is being used for depression of silica during flotation, has been used as grinding aid. The data indicates that at any given time of grind, the effect of grinding aid is significantly better as far as the separation efficiency of graphite. Hence, it is concluded that excessive size reduction of graphite is minimised while using a grinding aid. Based on these observations, further studies have been planned for flash flotation using a comminution circuit with grinding aids. The results of the present study reveals that number of cleaning of rougher concentrate alone will not fetch more than 75% of fixed carbon (FC) with less than 8% yield and 41% recovery. The effect of four stage cleanings continued with starvation dosage in grinding circuit followed by flash flotation indicate that the end product achieved contains 97.8% FC with 11.6% yield and 78% recovery and the overall values loss in tailings contain 3.6% FC. The end product achieved by alkali digestion method from a flotation product [97.8% FC] contains 99.2% FC with overall 10.4% yield and 71% recovery. The process adopted in the present investigation is friendly environment and process flowsheet is an innovative. The end product obtained from this process is useful for various industrial applications.
Mineral Processing
Chol Ung Ryom; Kwang Hyok Pak; Il Chol Sin; Kwang Chol So; Un Chol Han
Abstract
Scheelite ore with heavy and magnetic minerals can be generally concentrated using shaking table centered gravity-magnetic processing. When magnetic field is formed by fixing magnetic bars on which permanent magnets are arranged at a constant interval, above the table desk, heavy scheelite particles ...
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Scheelite ore with heavy and magnetic minerals can be generally concentrated using shaking table centered gravity-magnetic processing. When magnetic field is formed by fixing magnetic bars on which permanent magnets are arranged at a constant interval, above the table desk, heavy scheelite particles can be concentrated by gravity, whereas heavy magnetic mineral particles can be floated off like light mineral particles by upward magnetic force. In this paper, concentration of scheelite and removal of pyrrhotite floated by magnetic force was simulated using CFD for the sample containing 1% scheelite and 2% pyrrhotite, and compared with the experiment. As a result, WO3 grade and separation efficiency of concentrate were 65.3% and 80.1%, respectively, in the new table equipped with magnetic bars, whereas 28.4% and 76.5%, respectively, in conventional table. The magnetic field formed by fixing magnetic bars above table could be significant in simplifying the sequential tabling-magnetic separation process and reducing the loss of scheelite.
Mineral Processing
Nooshin Navi; Mohammad Karamoozian; Mohammad Reza Khani
Abstract
Red mud is an important solid tailing with strong alkalinity that is obtained during the extraction of alumina in the Bayer process. The global reserve of red mud is more than 4 billion tons, and its disposal as tailing has always been a serious environmental problem. This tailing is considered as a ...
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Red mud is an important solid tailing with strong alkalinity that is obtained during the extraction of alumina in the Bayer process. The global reserve of red mud is more than 4 billion tons, and its disposal as tailing has always been a serious environmental problem. This tailing is considered as a potential source, due to its high content of valuable metal compounds including iron. In this research work, the extraction of iron in red mud is investigated by the method of reduction roasting. The main influencing factors are also investigated. These methods include reduction in muffle and tube furnace, and temperature, reduction agent, and additive type are as important factors. Reduction roasting of the samples in a tube furnace, with Argon gas and vacuum, a mixture of red mud, graphite, and sodium carbonate at 700–1000 °C results in the formation of Fe3O4. Magnetic measurements indicate that saturation magnetization increases from 0.239 to 38.205 emu/g due to the formation of Fe3O4. Applying the magnetic field intensity of about 1000 Gauss results in the iron recovery of 89.9%.
Mineral Processing
Pedram Ashtari; Saeid Karimi; Seyyede Atefeh Hosseini
Abstract
In this research work, the reductive leaching of pyrolusite in a sulfuric acid medium with the aid of orange peel as a reductant was investigated. The important parameters affecting the leaching process include temperature in the range of 25 to 95 °C, the weight ratio of reducing agent to pyrolusite ...
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In this research work, the reductive leaching of pyrolusite in a sulfuric acid medium with the aid of orange peel as a reductant was investigated. The important parameters affecting the leaching process include temperature in the range of 25 to 95 °C, the weight ratio of reducing agent to pyrolusite (R/P) in the range of 0 to 2 (w/w), and the concentration of sulfuric acid in the range of 0.05 to 0.25 M. According to the results, the parameters of temperature and the R/P are more significant in the reductive leaching process. With increasing temperature from 25 to 95 °C, Mn recovery increases from 0.5% to 52.5%. Also Mn recovery with a two-step increase in 0-0.1 and 0.1-1.5 of the R/P indicates a jump of 28.5% and 19.0%, respectively. Sulfuric acid concentration shows its effect by supplying sulfate and hydrogen ions in the leaching process. The successful use of orange peel as a reductant was confirmed by achieving a manganese dissolution efficiency of 98.1% under optimum conditions (temperature of 90 °C, sulfuric acid concentration of 0.1 M, and R/P ratio of 1.5 (w/w)). Kinetic investigations showed that the shrinking core model could not be used to determine the leaching mechanism of pyrolusite in the presence of fruit peel reductant. Avrami's kinetic model with very high fitting accuracy was used to determine the kinetic model of pyrolusite leaching.
Mineral Processing
Aghil Haghdadi; Sima Mohammadnejad
Abstract
The presence of copper bearing minerals in cyanidation of gold ores may lead to several challenges in the CIP/CIL circuits. Many solutions have been proposed to address these problems, one being the use of glycine in the cyanidation process. Here, the experimental as well as molecular modelling studies ...
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The presence of copper bearing minerals in cyanidation of gold ores may lead to several challenges in the CIP/CIL circuits. Many solutions have been proposed to address these problems, one being the use of glycine in the cyanidation process. Here, the experimental as well as molecular modelling studies using Density Functional Theory (DFT) have been conducted to investigate the glycine role in cyanidation of copper bearing gold ores. The results show that in the presence of glycine in the solution containing copper-cyanide species and in very low or zero free cyanide content, the dissolution rate of gold is significantly improved (3.02 vs. 0.23 ppm), while no improvement is observed in copper free or cyanide enriched solutions. Molecular modeling has been performed to interpret the laboratory results as well as to identify the mechanisms. The modeling results demonstrate that in cyanide deficient solutions, cyanide complex of copper complexes (E = -319 kCal.mol-1) is replaced by glycine, and the free cyanide produced results in higher gold cyanidation as well as lower copper cyanide formation.
Mineral Processing
M. Diab; M. Abu El Ghar; I. Mohamed Gaafar; A. H. Mohamed El Shafey; A. Wageh Hussein; M. Mohamed Fawzy
Abstract
In this work we are concerned with the potentiality of using mineral processing for raising the grade of the valuable heavy minerals (VHMs) from the Quaternary stream sediments of Wadi and Delta Sermatai located on the southern coast of the Red Sea, Egypt. A rigorous understanding of the chemical and ...
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In this work we are concerned with the potentiality of using mineral processing for raising the grade of the valuable heavy minerals (VHMs) from the Quaternary stream sediments of Wadi and Delta Sermatai located on the southern coast of the Red Sea, Egypt. A rigorous understanding of the chemical and mineralogical characteristics of the studied samples is a prerequisite for the selection and development of the physical processing used in order to produce a high-grade concentrate. For this purpose, the grain size distribution analysis, heavy liquid separation tests as well as XRF, and SEM analysis are performed. The magnetite, ilmenite, garnet, zircon, rutile, apatite, sphene, pyrolusite, celestine, and heavy green silicates are the valuable heavy minerals recorded in the studied samples; but their quantity varies between Wadi and Delta. The upgrading experiments are performed via a shaking table in conjunction with the low and high-intensity magnetic separator in order to obtain the high-grade concentrates from the valuable heavy minerals, and after applying the optimum separation conditions, the total heavy mineral (THM) assay increase from 8.32% to 46.04% for Wadi Sermatai, while for Delta Sermatai increase from 8.37% to 50.13% into 8.89% and 9.59%, respectively, by mass yield. The THM recovery values reach 66.84% for Wadi Sermatai and 67.23% for Delta Sermatai. After the results of the chemical analysis of the concentrates, it is proved that the Sermatai area is considered as a potential source for some economic elements such as Fe, Ti, Zn, Zr, Cr, V, and Sr.
Mineral Processing
N. Khorasanizadeh; M. Karamoozian; H. Nouri-Bidgoli
Abstract
The bubble diameter effect on the bubble rise velocity profile in a flotation column is studied by the two-phase computational fluid dynamics (CFD) method. The simulations are done in the ANSYS® Fluent® software using a two-phase volume of fluid model. The computational domain is a square cross-section ...
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The bubble diameter effect on the bubble rise velocity profile in a flotation column is studied by the two-phase computational fluid dynamics (CFD) method. The simulations are done in the ANSYS® Fluent® software using a two-phase volume of fluid model. The computational domain is a square cross-section column with a 10 cm width and a 100 cm height, in which air is interred as a single bubble from the lower part of the column by an internal sparger. An experimental test is also performed, the hydrodynamics parameters are recorded, and the simulated results are validated using the values obtained for the bubble rise velocity. The simulation results obtained indicate that CFD can predict the bubble rise velocity profile and its value in the flotation column with less than 5% difference in comparison with the experimental results. Then the simulations are repeated for the other initial bubble diameter in the bubbly flow regime in order to study the bubble diameter effect on the rise velocity profile. The results obtained demonstrate that the larger bubbles reach the maximum velocity faster than the small ones, while the value of maximum velocity decreases by an increase in the bubble diameter. These results can be used to improve the flotation efficiency.
Mineral Processing
A.R. Javadi
Abstract
Carnallite, with the chemical formula KMgCl3.6H2O, is a mineral that was first discovered in the Urals Mountains in Russia. The reverse flotation has been established for carnallite processing in the current decades, and the alkyl morpholine collector is used for the removal of NaCl from carnallite using ...
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Carnallite, with the chemical formula KMgCl3.6H2O, is a mineral that was first discovered in the Urals Mountains in Russia. The reverse flotation has been established for carnallite processing in the current decades, and the alkyl morpholine collector is used for the removal of NaCl from carnallite using the reverse flotation. The carnallite processing method involves reverse flotation with the dodecyl morpholine collector, and then centrifugation and cold crystallization. In this research work, kimiaflot 619, as a new collector, is synthesized, and the bench-scale flotation shows that kimiaflot 619 reveals a better selectivity and affinity for the NaCl crystals at an acidic pH with a less collector dosages–only 1/2 of the Armoflot 619 collector. The flotation results indicate that the NaCl grade in carnallite concentrated by Armoflot 619 (200 g/t) is 2.86%, while the NaCl grade in carnallite concentrated by kimiaflot 619collector (100 g/t) is 2.75%. The frother’s stability of the Armoflot 619 collector after flotation is very high and uncontrollable, while kimiaflot 619 has solved this problem, and it is completely controllable.
Mineral Processing
S. Kolahi; M. Jahani Chegeni
Abstract
The number of lifters of mill shell liners, mill rotation speed, and filling percentage of grinding media are three of the most important parameters influencing the charge behavior and the trajectory of ball motion inside the SAG mills, and consequently, their performance. In this paper, the milling ...
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The number of lifters of mill shell liners, mill rotation speed, and filling percentage of grinding media are three of the most important parameters influencing the charge behavior and the trajectory of ball motion inside the SAG mills, and consequently, their performance. In this paper, the milling operation of pilot-scale SAG mills using the discrete element method (DEM) is investigated. First, a pilot-scale SAG mill with dimensions of 3.0 m × 1.5 m with no lifter is simulated. Then by adding, respectively, one, two, four, eight, sixteen, and thirty-two rectangle lifter(s), six other independent simulations are performed. The effects of the number of lifters on the two new parameters introduced by the authors, i.e. ‘head height’ and ‘impact zone length’ as well as on creation of cascading, cataracting, and centrifuging motions for balls at two different mill speeds, i.e. 70% and 80% of its critical speed (NC), are evaluated. Also in order to validate the simulation results, a laboratory-scale SAG mill is simulated. The results obtained indicate that the optimum number of lifters for pilot-scale SAG mills is between 16 and 32 lifters with medium thickness. Liners with the number of lifters in this range require less mill speed to create cataract motions. However, liners with the number of lifters less than this range require a higher mill speed. Also liners with the number of lifters beyond this range require less mill speed, and can cause centrifugal motions in the balls. Comparison of the simulations related to the laboratory-scale SAG mill with experimental results demonstrates a good agreement, which validates the DEM simulations and the software used.
